Attenuation of the NMR signal due to hydrodynamic Brownian motion

TL;DR

This paper derives a comprehensive all-time NMR signal attenuation function due to Brownian motion, revealing deviations from classical models at short times and enhancing understanding of particle dynamics in liquids.

Contribution

It introduces a model-independent calculation of NMR signal attenuation for all times using hydrodynamic Brownian motion theory.

Findings

Attenuation deviates from classical models at short times.

The derived formulas match classical behavior at long times.

Provides a new framework for interpreting NMR experiments in liquids.

Abstract

Nuclear magnetic resonance (NMR) is a widely used nondestructive method to study random motion of spin-bearing particles in different systems. In the long-time limit the theoretical description of the NMR experiments is well developed and allows proper interpretation of measurements of normal and anomalous diffusion. The traditional description becomes, however, insufficient for the shorter-time dynamics of the particles. In the present paper, the all-time attenuation function of the NMR signal in a magnetic-field gradient due to the Brownian motion (BM) of particles in incompressible liquids is calculated by using the method of accumulation of phases by a precessing magnetic moment, without reference to a concrete model of the stochastic dynamics. The obtained expressions are then used to evaluate the attenuation within the hydrodynamic theory of the BM. It is shown that the well-known time behavior of the formulas corresponding to the Einstein theory of diffusion in the case of steady gradient and Hahn's echo experiments is reached at times much larger than the characteristic time of the loss of memory in the particle dynamics. At shorter times the attenuation function significantly differs from the classical formulas used to interpret these experiments.