Photochemistry, mixing and transport in Jupiter's stratosphere constrained by Cassini

TL;DR

This study uses Cassini data and a 2D photochemical model to investigate how transport processes like diffusion and advection influence the distribution of key hydrocarbons in Jupiter's stratosphere, revealing complexities in their behavior.

Contribution

The paper develops a new 2D seasonal photochemical model incorporating transport processes to explain the latitudinal distribution of hydrocarbons in Jupiter's stratosphere.

Findings

C2H2 distribution is well reproduced without meridional diffusion.

Adding meridional diffusion improves C2H6 fit but worsens C2H2 fit.

Advective transport explains C2H6 increase with latitude but affects C2H2 distribution.

Abstract

We aim at constraining the diffusive and advective transport processes in Jupiter's stratosphere. The IR spectrum recorded by Cassini/CIRS during the Jupiter flyby contains the fingerprints of several atmospheric compounds and allows probing its atmospheric composition. C2H2 and C2H6, the main compounds produced by methane photochemistry, were retrieved as a function of latitude at certain pressure levels. CIRS observations suggest a different meridional distribution for these two species, difficult to reconcile with their photochemical histories, which are thought to be coupled to the methane photolysis. While the C2H2 abundance decreases with latitude, C2H6 becomes more abundant at high latitudes. A new 2D (latitude-altitude) seasonal photochemical model is developed to study whether the addition of stratospheric transport processes, such as meridional diffusion and advection, can explain the latitudinal behavior of C2H2 and C2H6. C2H2 observations are fairly well reproduced without meridional diffusion. Adding meridional diffusion to the model provides an improved agreement with the C2H6 observations by flattening its meridional distribution, but degrades the fit to the C2H2 distribution. Meridional diffusion alone cannot produce the observed increase with latitude of C2H6. When adding advective transport between 30 mbar and 0.01 mbar, with upwelling winds at the equator and downwelling winds at high latitudes, we can reproduce the C2H6 abundance increase with latitude. However, the fit to the C2H2 distribution is degraded. The strength of the advective winds needed to reproduce the C2H6 abundances is very sensitive to the value of the meridional eddy diffusion coefficient. The coupled fate of C2H2 and C2H6 suggests that an additional process is missing in the model. Ion-neutral chemistry was not accounted for in this work and might be a good candidate to solve this issue.