Quantifying the Trade-offs between Energy Consumption and Salt Removal Rate in Membrane-free Cation Intercalation Desalination

TL;DR

This study evaluates a membrane-free electrochemical desalination system using porous diaphragms, analyzing the trade-offs between energy efficiency and salt removal rate through modeling and simulations.

Contribution

It introduces a membrane-free design with a porous diaphragm, deriving equations to optimize charge efficiency and quantify energy-salt removal trade-offs.

Findings

Charge efficiency approaches the anion transference number with low salt conductance diaphragms.

Derived equations relate charge efficiency to Péclet and Damköhler numbers for system optimization.

Flow-through electrodes outperform other configurations in desalination degree due to better solution dynamics.

Abstract

Electrochemical desalination devices that use redox-active cation intercalation electrodes show promise for desalination of salt-rich water resources with high water recovery and low energy consumption. While previous modeling and experiments used ion-exchange membranes to maximize charge efficiency, here a membrane-free alternative is evaluated to reduce capital cost by using a porous diaphragm to separate Na$_{1+x}$NiFe(CN)$_6$ electrodes. Two-dimensional porous-electrode modeling shows that, while charge efficiency losses are inherent to a diaphragm-based architecture, charge efficiency values approaching the anion transference number (61$\%$ for NaCl) are achievable for diaphragms with sufficiently low salt conductance. Closed-form equations are thereby derived that relate charge efficiency to the non-dimensional P\`{e}clet and Damk\"ohler numbers that enable the selection of current and flow velocity to produce a desired degree of desalination. Simulations using these conditions are used to quantify the tradeoffs between energy consumption and salt removal rate for diaphragm-based cells operated at a range of currents. The simulated distributions of reactions are shown to result from the local salt concentration variations within electrodes using diffusion-potential theory. We also simulate the cycling dynamics of various flow configurations and show that flow-through electrodes exceed the degree-of-desalination compared with flow-by and flow-behind configurations due to solution stagnation within electrodes.