Dynamical screening in monolayer transition-metal dichalcogenides and its manifestations in the exciton spectrum

TL;DR

This paper reviews how dynamical screening and shortwave plasmons influence exciton spectra in monolayer transition-metal dichalcogenides, revealing new optical features and their relation to many-body interactions.

Contribution

It introduces a comprehensive model incorporating shortwave plasmons and dynamical screening effects into the exciton spectrum analysis of ML-TMDs, explaining experimental observations.

Findings

Coupling between excitons and shortwave plasmons explains optical sidebands.

Shortwave plasmons originate from short-range Coulomb interactions between valleys.

Spin ordering influences the optical features in electron-doped W-based MLs.

Abstract

Monolayer transition-metal dichalcogenides (ML-TMDs) offer exciting opportunities to test the manifestations of many-body interactions through changes in the charge density. Tuning the charge density by a gate voltage leads to profound changes in the optical spectra of excitons in ML-TMDs. We review the band-gap renormalization and dynamical screening as a function of charge density, and then incorporate these effects through various approximations that model long-wavelength charge excitations in the Bethe-Salpeter Equation (BSE). We then show that coupling between excitons and shortwave charge excitations is essential to resolve several experimental puzzles. Unlike ubiquitous and well-studied plasmons, driven by collective oscillations of the background charge density in the long-wavelength limit, we discuss the emergence of shortwave plasmons that originate from the short-range Coulomb interaction through which electrons transition between the $\mathbf{K}$ and $-\mathbf{K}$ valleys. We study the coupling between the shortwave plasmons and the neutral exciton through the self-energy of the latter. We then elucidate how this coupling as well as the spin ordering in the conduction band give rise to an experimentally observed optical sideband in electron-doped W-based MLs, conspicuously absent in electron-doped Mo-based MLs or any hole-doped ML-TMDs. While the focus of this review is on the optical manifestations of many-body effects in ML-TMDs, a systematic description of the dynamical screening and its various approximations allow one to revisit other phenomena, such as nonequilibrium transport or superconducting pairing, where the use of the BSE or the emergence of shortwave plasmons can play an important role.