Molecular reconnaissance of the $\beta$ Pictoris gas disk with the SMA: a low HCN/(CO+CO$_2$) outgassing ratio and predictions for future surveys
L. Matr\`a, D. J. Wilner, K. I. \"Oberg, S. M. Andrews, R. A. Loomis,, M. C. Wyatt, W. R. F. Dent

TL;DR
This study uses SMA and archival ALMA data to analyze the molecular composition of the $eta$ Pictoris gas disk, revealing a low HCN/(CO+CO$_2$) outgassing ratio and predicting future detectability of molecules like CN and HCN.
Contribution
It provides the first molecular survey of $eta$ Pictoris' gas disk, updates excitation models with UV fluorescence, and constrains the HCN/(CO+CO$_2$) ratio in exocometary outgassing.
Findings
Upper limits for several molecules including CN, HCN, HCO$^+$, N$_2$H$^+$, H$_2$CO, H$_2$S, CH$_3$OH, SiO, DCN.
CN is the most detectable molecule after CO, with an upper limit of <2.5% for HCN/(CO+CO$_2$) ratio.
Predictions that CN and HCN will be detectable with ALMA around $eta$ Pictoris.
Abstract
The exocometary origin of CO gas has been confirmed in several extrasolar Kuiper belts, with CO ice abundances consistent with Solar System comets. We here present a molecular survey of the Pictoris belt with the Submillimeter Array (SMA), reporting upper limits for CN, HCN, HCO, NH and HCO, as well as for HS, CHOH, SiO and DCN from archival ALMA data. Non-detections can be attributed to rapid molecular photodissociation due to the A-star's strong UV flux. CN is the longest-lasting and most easily detectable molecule after CO in this environment. We update our NLTE excitation model to include UV fluorescence, finding it plays a key role in CO and CN excitation, and use it to turn the SMA CN/CO flux ratio constraint into an upper limit of % on the HCN/(CO+CO) ratio of outgassing rates. This value is consistent with, but at the low end of, the…
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