Like-charge attraction in a one-dimensional setting: the importance of being odd

TL;DR

This paper explores the phenomenon of like-charge attraction in a one-dimensional model, highlighting the crucial role of the number of counterions and providing exact results suitable for undergraduate education.

Contribution

It introduces an exact, undergraduate-level analysis of like-charge attraction, emphasizing the importance of counterion parity in one-dimensional systems.

Findings

Parity of counterions influences attraction

Exact solutions demonstrate like-charge attraction

Counterintuitive effects are explained mathematically

Abstract

From cement cohesion to DNA condensation, a proper statistical physics treatment of systems with long range forces is important for a number of applications in physics, chemistry, and biology. We compute here the effective force between fixed charged macromolecules, screened by oppositely charged mobile ions (counterions). We treat the problem in a one dimensional configuration, that allows for interesting discussion and derivation of exact results, remaining at a level of mathematical difficulty compatible with an undergraduate course. Emphasis is put on the counter-intuitive but fundamental phenomenon of like-charge attraction, that our treatment brings for the first time to the level of undergraduate teaching. The parity of the number of counterions is shown to play a prominent role, which sheds light on the binding mechanism at work when like-charge macromolecules do attract.