First detection of cyanamide (NH$_2$CN) towards solar-type protostars

TL;DR

This study reports the first detection of cyanamide in the warm gas around solar-type protostars, revealing its abundance and isotopologues, and explores its formation pathways via grain-surface chemistry.

Contribution

First detection of cyanamide and its isotopologues in solar-type protostars, with analysis of deuteration and formation mechanisms through chemical modeling.

Findings

Cyanamide detected in two solar-type protostars.

Deuteration level of cyanamide similar to formamide.

Grain-surface chemistry can reproduce observed cyanamide abundance.

Abstract

Searches for the prebiotically-relevant cyanamide (NH$_2$CN) towards solar-type protostars have not been reported in the literature. We here present the first detection of this species in the warm gas surrounding two solar-type protostars, using data from the Atacama Large Millimeter/Submillimeter Array Protostellar Interferometric Line Survey (PILS) of IRAS 16293-2422 B and observations from the IRAM Plateau de Bure Interferometer of NGC1333 IRAS2A. We furthermore detect the deuterated and $^{13}$C isotopologues of NH$_2$CN towards IRAS 16293-2422 B. This is the first detection of NHDCN in the interstellar medium. Based on a local thermodynamic equilibrium analysis, we find that the deuteration of cyanamide ($\sim$ 1.7%) is similar to that of formamide (NH$_2$CHO), which may suggest that these two molecules share NH$_2$ as a common precursor. The NH$_2$CN/NH$_2$CHO abundance ratio is about 0.2 for IRAS 16293-2422 B and 0.02 for IRAS2A, which is comparable to the range of values found for Sgr B2. We explored the possible formation of NH$_2$CN on grains through the NH$_2$ + CN reaction using the chemical model MAGICKAL. Grain-surface chemistry appears capable of reproducing the gas-phase abundance of NH$_2$CN with the correct choice of physical parameters.