Thermoelectric Power of the CeCoAl$_4$ Antiferromagnet - Predominance of the Crystal Electric Field

TL;DR

This study investigates the thermoelectric properties of CeCoAl4, revealing a significant crystal electric field influence on thermopower and proposing a comprehensive model incorporating CEF levels, contrasting with nonmagnetic LaCoAl4.

Contribution

It introduces a full CEF levels scheme to explain thermoelectric behavior in CeCoAl4, highlighting the CEF's dominant role in thermopower.

Findings

Large CEF-related peak in thermopower at 240K

Peak position close to upper CEF excitation energy

Phonon drag contribution observed in LaCoAl4

Abstract

We report on the thermoelectric power $S(T)$, electrical resistivity and thermal conductivity measurements on the antiferromagnetic CeCoAl$_4$ compound. The N\'eel temperature of CeCoAl$_4$ is $T_N$=13.5K and a metamagnetic-like transition occurs in the magnetic field of about 7.5T. We show that the magnetic contribution to the thermoelectric power, $S_f(T)$, exhibits a large peak due to the crystal electric field (CEF) at about 240K and a small anomaly around the ordering temperature. Surprisingly, the CEF related $S_f(T)$ peak is close to the upper CEF excitation energy $\Delta_2$=202K, in contrast to the usual case of the peak position being a fraction of the real CEF excitation. The applicability of different theoretical and phenomenological models describing the temperature dependence of the Seebeck effect $S_f(T)$ has been tested and finally a calculation is proposed, which incorporates a full CEF levels scheme. For the nonmagnetic reference compound, LaCoAl$_4$, the thermoelectric power measurements provide an evidence of the phonon drag contribution, which is not present or masked in the case of CeCoAl$_4$.