On curing silicone elastomers with a plasticising solvent

TL;DR

This study investigates the mechanical behavior of plasticised silicone elastomers, demonstrating a simple mixture law, and explores their potential for tissue-like deformation modeling through compression tests and structural analysis.

Contribution

It provides new insights into the deformation regimes of plasticised silicone elastomers and assesses their suitability for mimicking biological tissue behavior.

Findings

Material behavior follows a simple law of mixtures.

Distinct deformation regimes under compression were identified.

Recovery effects on elastic properties were analyzed.

Abstract

There is a growing interest in producing materials with mechanical behaviours similar to those of internal organs. An artificial tissue may be expected to experience several types of compressive and shear deformation in the course of normal usage. Thus research into mechanical modelling of these types of materials which behave similar to biological tissues, or can be used in making implants, is of importance to understand their usability and performance when subjected to different types of stresses. Here we study the behaviour of plasticised silicone elastomers and comment on the feasibility for modelling the behaviour of tissues. We perform compression tests on samples made of a silicone elastomer which is diluted with (plasticiser) silicone oil in the cross-linking stage. We show that the modification of material broadly follows a simple law of mixtures. Further, we use samples with a specific periodic structure which has neatly separated behavioural regimes under compression where it first extends outwards and then undergoes internal buckling. In terms of material behaviour, this results in two neatly separated regimes where the deformation is averaged throughout the length in the first regime, and highly localised in the later regime. This allows us to disentangle the two types of deformations (simple compression and shear of the same material) and study how the recovery of the material upon re-crosslinking, if any, affects its elastic properties.