Magnetocaloric Effect and Magnetic refrigeration: analytic and numeric study

TL;DR

This paper presents an analytical and numerical investigation of the magnetocaloric effect, focusing on material properties and microscopic parameters to optimize magnetic refrigeration performance near room temperature.

Contribution

It introduces a combined analytical and numerical approach to analyze the magnetocaloric effect using a spin Hamiltonian, aiding in the design of efficient magnetic refrigerants.

Findings

Identified key microscopic parameters influencing MCE performance

Demonstrated the role of exchange interaction and anisotropy in optimizing RCP

Proposed extension to composite materials for giant MCE at room temperature

Abstract

This work aims to present an analytical and numerical study of the magnetocaloric effects (MCE) providing realistic proposals about materials that should be chosen in the design of new refrigerator appliances around the room temperature. Starting from a spin Hamiltonian including the exchange interaction, the single-ion anisotropy and the applied magnetic field terms, we have calculated the partition function at a given temperature and derived a set of relevant physical quantities as magnetization, magnetic entropy and specific heat and analyzed their behavior with atomic parameters as spin, exchange and anisotropy. Using numerical programs that we developed by ourselves, we were able to better elucidate the role of each microscopic parameter in order to reinforce the relative cooling power (RCP) and give rise to optimal performances of the refrigerant compound. This approach could be extended to composite materials underscoring a giant MCE at room temperature. Key-words Magnetic refrigeration, Magnetocaloric Effect, Energy efficiency, Spin Hamiltonian