Dendritic Growth of a Polymer on a 2D Mesoscale Square Lattice

TL;DR

This study investigates dendritic growth patterns of polyethylene oxide on patterned substrates, combining experimental observations with phase-field simulations to understand how substrate patterning influences anisotropic growth during phase segregation.

Contribution

It introduces a combined experimental and numerical approach to analyze how substrate patterning affects dendritic growth anisotropy in polymers.

Findings

Dendritic growth exhibits four-fold anisotropy on flat substrates.

Patterned substrates induce eight-fold anisotropy in polymer growth.

Simulations qualitatively match experimental dendritic structures.

Abstract

Dendritic growth patterns exhibiting four-fold anisotropy are observed when polyethylene oxide undergoes phase segregation from a solution phase to a solid phase. When this phase transition occurs on a substrate that has patterns of cross-linked polyethylene oxide resist pillars made using electron beam lithography, the polymer grows in between the patterns giving rise to dendritic growth structures exhibiting eight-fold anisotropy. This paper presents these experimental observations and explains the dendritic growth using principles of minimization of free energy associated with phase change. Numerical simulations are carried out using phase-field modeling, and the results are shown to qualitatively match experimental observations. The simulations reveal that the polymer assumes the anisotropy of the patterned lattice.