Numerical investigation into the effects of non-equilibrium plasma discharge on two-stage ignition and LTC of DME/O2/Ar Mixtures

TL;DR

This study numerically examines how nanosecond pulsed non-equilibrium plasma discharges influence ignition delay and low-temperature chemistry of DME/O2/Ar mixtures, revealing significant improvements and pathway alterations across different temperature regimes.

Contribution

It introduces a detailed multi-timescale plasma-discharge model to analyze plasma effects on two-stage ignition and LTC in DME mixtures at various temperatures.

Findings

Plasma reduces ignition delay by up to 15 times in NTC regime.

In intermediate temperatures, plasma reactivates two-stage ignition, shortening delay by 75 times.

Optimal plasma energy input occurs with 35-40 voltage pulses.

Abstract

The effects of nanosecond pulsed non-equilibrium plasma discharges on ignition characteristics and low-temperature chemistry or LTC of DME/O2/Ar mixtures are numerically investigated in a plane-to-plane geometry at a reduced pressure of 76 Torr. Detailed numerical investigations of the two-stage ignition process in different temperature regimes of DME have been created through a high-fidelity one-dimensional, multi-timescale plasma-discharge model. Two different initial temperatures are set for comparison: 550K, the negative temperature coefficient regime, where LTC plays a dominate role; 800K, the intermediate temperature regime, where LTC normally does not play an important role. The results have shown that, in NTC regime, non-equilibrium plasma discharge improves the overall ignition delay time by 15 times with a significant improvement of approximately 250 times for the first-stage ignition. In Intermediate temperature regime, the two-stage ignition property is reactivated by the addition of plasma, and the overall ignition delay is shortened by approximately 75 times. This observation suggests that, in the intermediate temperature regime, the plasma discharges can not only enhance DME ignition characteristics but also alter the reaction pathways to a reactive LTC reaction pathway; therefore, the two-stage ignition behavior occurred again. Further investigation suggests that the plasma enhancement on ignition and LTC in the intermediate temperature regime is non-linear. As the accumulative energy input to the system increases, the enhancement from the non-equilibrium plasma discharge reaches a limit. Considering the total amount of heat release, the optimized voltage pulse number appears to be in the range of 35-40 to provide the most efficient enhancement for the overall ignition delay time.