Leakage Processes in Damaged Shale: In Situ Measurements of Permeability, CO$_2$-Sorption Behavior and Acoustic Properties

TL;DR

This paper investigates the permeability, CO2 sorption, and acoustic properties of damaged shale to assess caprock integrity and leakage risks in CO2 storage, highlighting experimental findings on permeability differences and detection methods.

Contribution

It provides new in situ measurements of permeability, sorption behavior, and acoustic responses of damaged shale, advancing understanding of caprock integrity in CO2 sequestration.

Findings

Permeability varies by up to three orders of magnitude between brittle and ductile fractures.

CO2 sorption onto shale may mitigate leakage in damaged caprock.

CO2 saturation significantly reduces the bulk modulus of shale, detectable via acoustic methods.

Abstract

Caprock integrity is one of the chief concerns in the successful development of a CO$_2$ storage site. In this chapter, we provide an overview of the permeability of fractured shale, the potential for mitigation of CO$_2$ leakage by sorption to shale, and the detection by acoustic methods of CO$_2$ infiltration into shale. Although significant concerns have been raised about the potential for induced seismicity to damage caprock, relatively little is known about the permeability of the damaged shale. We present a summary of recent experimental work that shows profound differences in permeability of up to three orders of magnitude between brittle and ductile fracture permeability. In the ductile regime, it is possible that shale caprock could accommodate deformation without a significant loss of CO$_2$ from the storage reservoir. In cases where CO$_2$ does migrate through damaged shale caprock, CO$_2$ sorption onto shale mineralogy may have a mitigating impact. Measured total storage capacities range from 1 to 45 kg-CO$_2$/tonne-shale. Once CO$_2$ is in the caprock, changes in the acoustic properties of CO$_2$-saturated shale that are predicted by Gassmann fluid substitution calculations show a significant reduction of the bulk modulus of CO$_2$-saturated shale.