Sensing phase-transitions via nitrogen-vacancy centers in diamond

TL;DR

This paper proposes using nitrogen-vacancy centers in diamond as highly sensitive, non-invasive sensors to detect phase transitions and structural features of liquids at the nanoscale, overcoming experimental challenges.

Contribution

It introduces a theoretical and numerical framework predicting NV centers' ability to detect phase transitions in liquids at the nanoscale, a novel application of quantum sensing technology.

Findings

NV centers can detect magnetic signals from liquids and solids on diamond surfaces.

Theoretical predictions show NV centers can resolve water phase transitions at the nanoscale.

Numerical evidence supports the feasibility of sensing structural water features.

Abstract

Ultra-thin layers of liquids on a surface behave differently from bulk liquids due to liquid-surface interactions. Some examples are significant changes in diffusion properties and the temperature at which the liquid-solid phase transition takes place. Indeed, molecular dynamics simulations suggest that thin layers of water on a diamond surface may remain solid even well above room temperature. However, because of the small volumes that are involved, it is exceedingly difficult to examine these phenomena experimentally with current technologies. In this context, shallow NV centers promise a highly sensitive tool for the investigation of magnetic signals emanating from liquids and solids that are deposited on the surface of a diamond. Moreover, NV centers are non-invasive sensors with extraordinary performance even at room-temperature. To that end, we present here a theoretical work, complemented with numerical evidence based on bosonization techniques, that predicts the measurable signal from a single NV center when interacting with large spin baths in different configurations. We therefore propose single NV centers as sensors capable to resolve structural water features at the nanoscale and even sensitive to phase transitions.