Structural, Electrical, and Magnetic Properties of La2Ni1.5Mn0.5O6 double perovskites

TL;DR

This study investigates how altering the Ni:Mn ratio in La2NiMnO6 double perovskites affects their structural, magnetic, and electrical properties, revealing new insights into their potential for device applications.

Contribution

It reports the synthesis and characterization of La2Ni1.5Mn0.5O6 with a non-stoichiometric Ni:Mn ratio, highlighting changes in structure, magnetism, and conductivity compared to the stoichiometric compound.

Findings

Monoclinic structural phase with partial disorder.

Ferromagnetic ordering around 260 K.

Semiconducting behavior confirmed by resistivity and I-V measurements.

Abstract

Among multifunctional double perovskite oxides, La2NiMnO6 has recently drawn significant attention due to its importance both in terms of understanding of fundamental physics and potential for device applications. The relative alteration in Ni:Mn ratio strongly influences the structural, magnetic and electrical properties of La2NiMnO6. In the present study, La2Ni1.5Mn0.5O6 sample with Ni:Mn = 3:1 ratio has been prepared using sol-gel method and modifications of the above physical properties from that of a stiochiometric sample of La2NiMnO6 are discussed. Rietveld analysis of X-ray diffraction data shows that La2Ni1.5Mn0.5O6 samples belong to a major monoclinic structural phase (P21/n), with partially disordered arrangement of Ni and Mn ions. Magnetic characterization and X-ray absorption near edge structure analysis reveal ferromagnetic ordering around 260 K between Ni2+ and Mn4+ ions while spin glass like behavior is revealed at ~45 K. Semiconducting nature of the sample was confirmed from temperature dependent resistivity measurements as well as from the I-V characteristics measured at room temperature.