High-Resolution Spectroscopic Detection of TiO and Stratosphere in the Day-side of WASP-33b
Stevanus K. Nugroho, Hajime Kawahara, Kento Masuda, Teruyuki Hirano,, Takayuki Kotani, and Akito Tajitsu

TL;DR
This study uses high-resolution spectroscopy to detect TiO molecules and infer a stratosphere in the atmosphere of the hot Jupiter WASP-33b, demonstrating the effectiveness of optical high-dispersion methods for exoplanet atmospheric characterization.
Contribution
First detection of TiO in WASP-33b's atmosphere using high-resolution optical spectroscopy, confirming a temperature inversion and demonstrating the technique's potential for exoplanet studies.
Findings
TiO detected at 4.8-sigma significance
Confirmed presence of stratosphere in WASP-33b
Refined orbital velocity constraints
Abstract
We report high-resolution spectroscopic detection of TiO molecular signature in the day-side spectra of WASP-33 b, the second hottest known hot Jupiter. We used High-Dispersion Spectrograph (HDS; R 165,000) in the wavelength range of 0.62 -- 0.88 m with the Subaru telescope to obtain the day-side spectra of WASP-33 b. We suppress and correct the systematic effects of the instrument, the telluric and stellar lines by using SYSREM algorithm after the selection of good orders based on Barnard star and other M-type stars. We detect a 4.8- signal at an orbital velocity of = +237.5 km s and systemic velocity = -1.5 km s, which agree with the derived values from the previous analysis of primary transit. Our detection with the temperature inversion model implies the existence of stratosphere in its…
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