On the matrix factorization of many-particle Coulomb Hamiltonians
Alexei M. Frolov

TL;DR
This paper demonstrates that many-particle Coulomb Hamiltonians can always be factorized, enabling analytical formulas for bound state spectra of complex atomic systems, similar to the hydrogen atom's Bohr formula.
Contribution
It introduces a universal factorization method for many-particle Coulomb Hamiltonians, leading to explicit spectral formulas for complex atomic systems.
Findings
Factorization of Coulomb Hamiltonians is always possible.
Analytical formulas for bound states are derived for arbitrary many-particle systems.
Formulas resemble Bohr's formula for hydrogen, extending its applicability.
Abstract
It is shown that the Coulomb many-particle Hamiltonians are always factorized. This fact can be used to obtain the closed analytical formula(s) for the bound state spectra of an arbitrary many-particle Coulomb system. For few- and many-electron atoms and ions these formulas are similar in some sense to the Bohr's formula which describes the bound state spectra of the hydrogen atom.
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Taxonomy
TopicsAdvanced Physical and Chemical Molecular Interactions · Advanced Chemical Physics Studies · Atomic and Molecular Physics
