Spontaneous $CP$ breaking in QCD and the axion potential: an effective Lagrangian approach
Paolo Di Vecchia, Giancarlo Rossi, Gabriele Veneziano, Shimon, Yankielowicz

TL;DR
This paper investigates the conditions under which QCD spontaneously breaks CP symmetry at a vacuum angle of π, revealing phase transitions and their implications for axion physics and dark matter models.
Contribution
It provides a detailed analysis of CP breaking regions in QCD's effective Lagrangian, highlighting the impact on axion potential calculations and dark matter implications.
Findings
Identification of first and second order phase transitions at θ=π
Existence of a second order critical point at the end of a first order line
Implications for axion potential calculations in CP-broken regions
Abstract
Using the well-known low-energy effective Lagrangian of QCD --valid for small (non-vanishing) quark masses and a large number of colors-- we study in detail the regions of parameter space where is spontaneously broken/unbroken for a vacuum angle . In the -broken region there are first order phase transitions as one crosses , while on the (hyper)surface separating the two regions, there are second order phase transitions signaled by the vanishing of the mass of a pseudo Nambu-Goldstone boson and by a divergent QCD topological susceptibility. The second order point sits at the end of a first order line associated with the spontaneous breaking, in the appropriate complex parameter plane. When the effective Lagrangian is extended by the inclusion of an axion these features of QCD imply that standard calculations of the axion potential have to be…
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