Photo-physical properties of He-related color centers in diamond

TL;DR

This study systematically investigates the photo-physical properties of He-related color centers in diamond, revealing their spectral features, lifetimes, and Stark effect responses, advancing understanding for quantum photonics applications.

Contribution

It provides the first detailed analysis of He-related defect structures in diamond, including their spectral, temporal, and electric field response properties, aiding future quantum device development.

Findings

He-related centers exhibit distinct emission lines at 535 nm and 560 nm.

Measured emission lifetimes are approximately 29 ns and 106 ns.

External electric fields cause Stark shifts indicating non-inversion symmetric defect structures.

Abstract

Diamond is a promising platform for the development of technological applications in quantum optics and photonics. The quest for color centers with optimal photo-physical properties has led in recent years to the search for novel impurity-related defects in this material. Here, we report on a systematic investigation of the photo-physical properties of two He-related (HR) emission lines at 535 nm and 560 nm created in three different diamond substrates upon implantation with 1.3 MeV He+ ions and subsequent annealing. The spectral features of the HR centers were studied in an "optical grade" diamond substrate as a function of several physical parameters, namely the measurement temperature, the excitation wavelength and the intensity of external electric fields. The emission lifetimes of the 535 nm and 560 nm lines were also measured by means of time-gated photoluminescence measurements, yielding characteristic decay times of (29 +- 5) ns and (106 +- 10) ns, respectively. The Stark shifting of the HR centers under the application of an external electrical field was observed in a CVD diamond film equipped with buried graphitic electrodes, suggesting a lack of inversion symmetry in the defects' structure. Furthermore, the photoluminescence mapping under 405 nm excitation of a "detector grade" diamond sample implanted at a 1x1010 cm-2 He+ ion fluence enabled to identify the spectral features of both the HR emission lines from the same localized optical spots. The reported results provide a first insight towards the understanding of the structure of He-related defects in diamond and their possible utilization in practical applications