Conservation laws and constitutive equations for an electro-active polymer

TL;DR

This paper develops a comprehensive multiphysics model for ionic electro-active polymers, integrating electro-mechanical-chemical couplings using conservation laws and thermodynamics to describe their behavior as sensors and actuators.

Contribution

It introduces a detailed continuum model combining Maxwell's equations, conservation laws, and thermodynamics for electro-active polymers, advancing understanding of their multiphysics interactions.

Findings

Derived constitutive equations for electro-mechanical-chemical couplings.

Modeled the behavior of water-saturated ionic polymers as deformable porous media.

Provided a framework for predicting polymer responses to electric stimuli.

Abstract

Ionic electro-active polymer (Nafion for example) can be used as sensor or actuator. To this end, a thin film of the water-saturated material is sandwiched between two electrodes. Water saturation causes a quasi-complete dissociation of the polymer and the release of small cations. The application of an electric field across the thickness results in the bending of the strip. Conversely, a voltage can be detected between the two electrodes when the strip is bent. This phenomenon involves multiphysics couplings of electro-mechanical-chemical type. The system is modeled by a deformable porous medium in which flows an ionic solution and we use a continuous medium approach. Maxwell's equations and conservation laws of mass, linear momentum and energy are first written at the microscopic scale for each phase and interfaces, then for the complete material using an average technique. Thermodynamics of linear irreversible processes provides the constitutive equations : a Kelvin-Voigt stress-strain relation,generalized Fourier's and Darcy's laws and a Nernst-Planck equation.