Magnetic properties of monoclinic lanthanide metaborates, $Ln$(BO$_2$)$_3$, $Ln$ = Pr, Nd, Gd, Tb

TL;DR

This study investigates the magnetic properties of lanthanide metaborates, revealing diverse magnetic behaviors including low-dimensional magnetism, magnetic ordering, and magnetisation plateaus, with implications for understanding magnetic frustration and quantum phenomena.

Contribution

It provides the first comprehensive magnetic characterization of $Ln$(BO$_2$)$_3$ compounds, highlighting their low-dimensional magnetic features and field-induced phenomena.

Findings

Gd(BO$_2$)$_3$ shows magnetic ordering at 1.1 K.

Tb(BO$_2$)$_3$ exhibits two magnetic transitions at 1.05 K and 1.95 K.

Nd(BO$_2$)$_3$ and Tb(BO$_2$)$_3$ display a magnetisation plateau at one-third saturation.

Abstract

The bulk magnetic properties of the lanthanide metaborates, $Ln$(BO$_2$)$_3$, $Ln$ = Pr, Nd, Gd, Tb are studied using magnetic susceptibility, heat capacity and isothermal magnetisation measurements. They crystallise in a monoclinic structure containing chains of magnetic $Ln^{3+}$ and could therefore exhibit features of low-dimensional magnetism and frustration. Pr(BO$_2$)$_3$ is found to have a non-magnetic singlet ground state. No magnetic ordering is observed down to 0.4 K for Nd(BO$_2$)$_3$. Gd(BO$_2$)$_3$ exhibits a sharp magnetic transition at 1.1 K, corresponding to three-dimensional magnetic ordering. Tb(BO$_2$)$_3$ shows two magnetic ordering features at 1.05 K and 1.95 K. A magnetisation plateau at a third of the saturation magnetisation is seen at 2 K for both Nd(BO$_2$)$_3$ and Tb(BO$_2$)$_3$ which persists in an applied field of 14 T. This is proposed to be a signature of quasi one-dimensional behaviour in Nd(BO$_2$)$_3$ and Tb(BO$_2$)$_3$.