Strong-coupling charge density wave in a one-dimensional topological metal

TL;DR

This study reveals a strong-coupling charge density wave in a one-dimensional topological metal surface, driven by phonon entropy rather than electronic nesting, challenging conventional expectations for such systems.

Contribution

It demonstrates a phonon-driven, strong-coupling charge density wave in a one-dimensional topological surface, contrary to typical nesting-driven mechanisms.

Findings

Observation of dimerization-like reconstruction at low temperatures.

Absence of electronic structure changes near the Fermi surface.

Structural transition driven by phonon entropy, not electronic nesting.

Abstract

Scanning tunnelling microscopy and low energy electron diffraction show a dimerization-like reconstruction in the one-dimensional atomic chains on Bi(114) at low temperatures. While one-dimensional systems are generally unstable against such a distortion, its observation is not expected for this particular surface, since there are several factors that should prevent it: One is the particular spin texture of the Fermi surface, which resembles a one-dimensional topological state, and spin protection should hence prevent the formation of the reconstruction. The second is the very short nesting vector $2 k_F$, which is inconsistent with the observed lattice distortion. A nesting-driven mechanism of the reconstruction is indeed excluded by the absence of any changes in the electronic structure near the Fermi surface, as observed by angle-resolved photoemission spectroscopy. However, distinct changes in the electronic structure at higher binding energies are found to accompany the structural phase transition. This, as well as the observed short correlation length of the pairing distortion, suggest that the transition is of the strong coupling type and driven by phonon entropy rather than electronic entropy.