Studies on dielectric relaxation in ceramic multiferroic Gd1-xYxMnO3

TL;DR

This study investigates dielectric relaxation in ceramic Gd1-xYxMnO3 across temperatures, revealing a ferroelectric transition at ~18K and non-Debyean relaxation behavior with critical slowdown near the transition.

Contribution

It provides detailed dielectric analysis of Gd1-xYxMnO3 ceramics, highlighting the non-linear relaxation dynamics and critical phenomena associated with ferroelectric transition.

Findings

Sharp dielectric peak at ~18K indicating ferroelectric transition

Non-Debyean relaxation with nonlinear temperature dependence of relaxation time

Critical slowdown of relaxations near the ferroelectric transition

Abstract

Dielectric study over a broadband was carried out from 10 to 70 K on ceramic Gd1-xYxMnO3 (x= 0.2, 0.3, and 0.4). For all the compositions, a prominent sharp peak about ~18K was observed in the temperature dependence of both {\epsilon}'(T) and {\epsilon}"(T) at all frequencies, indicating a long-range ferroelectric (FE) transition. Using Cole-Cole fit to the permittivity data, the relaxation time {\tau} and the dielectric strength {\Delta}{\epsilon} were estimated. Temperature variation of {\tau}(T) in the Arrhenius representation is found to be nonlinear (non-Debyean relaxation), with increasing barrier-activation energy over successive temperature-windows. Interestingly, for all the compositions, we witness a jump in {\tau}(T) about the ferroelectric transition temperature, concurred by a broad-maximum in {\Delta}{\epsilon}(T), signifying the critical slowdown of relaxations near long-range FE-correlations.