# New 3,3'-(ethane-1, 2-diylidene)bis(indolin-2-one) (EBI)-based small molecule semiconductors for organic solar cells

## TL;DR

This study introduces novel EBI-based small molecules for organic solar cells, demonstrating their synthesis, characterization, and application in BHJ devices with up to 1.92% efficiency, highlighting structure-property relationships.

## Contribution

The paper reports the design, synthesis, and application of new EBI-based small molecules with improved charge transport and photovoltaic performance in organic solar cells.

## Key findings

- EBI-BF exhibits perfect planarity and high hole mobility.
- EBI-2T achieves a maximum PCE of 1.92%.
- Molecular structure influences film morphology and device efficiency.

## Abstract

A series of donor-acceptor-donor (D-A-D) structured small-molecule compounds, with 3,3'-(ethane-1,2-diylidene)bis(indolin-2-one) (EBI) as a novel electron acceptor building block coupled with various electron donor end-capping moieties (thiophene, bithiophene and benzofuran), were synthesized and characterized. When the fused-ring benzofuran is combined to EBI (EBI-BF), the molecules displayed a perfectly planar conformation and afforded the best charge tranport properties among these EBI compounds with a hole mobility of up to 0.021 cm2 V-1 s-1. All EBI-based small molecules were used as donor material along with a PC61BM acceptor for the fabrication of solution-processed bulk-heterojunction (BHJ) solar cells. The best performing photovoltaic devices are based on the EBI derivative using the bithiophene end-capping moiety (EBI-2T) with a maximum power conversion efficiency (PCE) of 1.92%, owing to the broad absorption spectra of EBI-2T and the appropriate morphology of the BHJ. With the aim of establishing a correlation between the molecular structure and the thin film morphology, differential scanning calorimetry, atomic force microscopy and X-ray diffraction analysis were performed on neat and blend films of each material.

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Source: https://tomesphere.com/paper/1706.08074