Multiscale modeling strategy and general theory of non-equilibrium plasma assisted ignition and combustion

TL;DR

This paper presents a comprehensive multiscale theoretical framework for plasma-assisted ignition and combustion, incorporating a novel modeling approach and a general theory dividing the process into four distinct stages.

Contribution

It introduces a self-consistent 1D modeling framework with a frozen electric field approach, dynamic chemistry acceleration, and a multitimescale strategy, along with a general theory of plasma discharges in ignition.

Findings

The four stages of nanosecond pulsed plasma discharges are characterized by distinct timescales and mechanisms.

The framework effectively captures energy coupling, radical generation, and gas heating processes across stages.

Plasma significantly enhances radical production and preheating, promoting autoignition in flames.

Abstract

A selfconsistent 1D theoretical framework for plasma assisted ignition and combustion is reviewed. In this framework, a frozen electric field modeling approach is applied to take advantage of the quasiperiodic behaviors of the electrical characteristics to avoid the recalculation of electric field for each pulse. The correlated dynamic adaptive chemistry (CoDAC) method is employed to accelerate the calculation of large and stiff chemical mechanisms. The timestep is updated dynamically during the simulation through a three-stage multitimescale modeling strategy, which takes advantage of the large separation of timescales in nanosecond pulsed plasma discharges. A general theory of plasma assisted ignition and combustion is then proposed. Nanosecond pulsed plasma discharges for ignition and combustion can be divided into four stages. Stage I is the discharge pulse, with timescales of O(1 to 10 ns). In this stage, most input energy is coupled into electron impact excitation and dissociation reactions to generate charged or excited species and radicals. Stage II is the afterglow during the gap between two adjacent pulses, with timescales of O(100 ns). In this stage, quenching of excited species not only further dissociates O2 and fuel molecules, but also provides fast gas heating. Stage III is the remaining gap between pulses, with timescales of O(1 to 100 microsec). The radicals generated during Stages I and II significantly enhance the exothermic reactions in this stage. Stage IV is the accumulative effects of multiple pulses, with timescales of O(1 ms to 1 sec), which include preheated gas temperatures and a large pool of radicals and fuel fragments to trigger ignition. For plasma assisted flames, plasma significantly enhances the radical generation and gas heating in the preheat zone, which could trigger upstream autoignition.