# Retrieving Neptune's aerosol properties from Keck OSIRIS observations. I. Dark regions

## TL;DR

This study uses high-resolution spectroscopic data from Keck OSIRIS to analyze Neptune's dark atmospheric regions, revealing details about aerosol layers and methane distribution, with implications for understanding Neptune's atmospheric composition and structure.

## Contribution

First detailed analysis of Neptune's aerosol and methane profiles in dark regions using 3D data cubes and advanced modeling techniques.

## Key findings

- Neptune's cloud opacity is dominated by a compact, optically thick cloud near 3 bar.
- A vertically extended haze of small particles exists above the deep cloud.
- Aerosol optical depth decreases significantly from low to high southern latitudes.

## Abstract

We present and analyze three-dimensional data cubes of Neptune from the OSIRIS integral-field spectrograph on the 10-m Keck telescope, from July 2009. These data have a spatial resolution of 0.035"/pixel and spectral resolution of R~3800 in the H and K broad bands. We focus our analysis on regions of Neptune's atmosphere that are near-infrared dark- that is, free of discrete bright cloud features. We use a forward model coupled to a Markov chain Monte Carlo algorithm to retrieve properties of Neptune's aerosol structure and methane profile above ~4 bar in these near-infrared dark regions. Using a set of high signal-to-noise spectra in a cloud-free band from 2-12N, we find that Neptune's cloud opacity is dominated by a compact, optically thick cloud layer with a base near 3 bar and composed of low albedo, forward scattering particles, with an assumed characteristic size of ~1$\mu$m. Above this cloud, we require a vertically extended haze of smaller (~0.1 $\mu$m) particles, which reaches from the upper troposphere (~0.6 bar) into the stratosphere. The particles in this haze are brighter and more isotropically scattering than those in the deep cloud. When we extend our analysis to 18 cloud-free locations from 20N to 87S, we observe that the optical depth in aerosols above 0.5 bar decreases by a factor of 2-3 or more at mid- and high-southern latitudes relative to low latitudes. We also consider Neptune's methane (CH$_4$) profile, and find that our retrievals indicate a strong preference for a low methane relative humidity at pressures where methane is expected to condense. Our preferred solution at most locations is for a methane relative humidity below 10% near the tropopause in addition to methane depletion down to 2.0-2.5 bar. We tentatively identify a trend of lower CH$_4$ columns above 2.5 bar at mid- and high-southern latitudes over low latitudes.