The edge delamination of monolayer transition metal dichalcogenides

TL;DR

This paper investigates edge delamination and buckling behaviors in monolayer transition metal dichalcogenides caused by thermal mismatch, revealing universal patterns and their implications for future applications of 2D materials.

Contribution

It introduces a detailed analysis of edge delamination patterns in monolayer TMDs, linking experimental observations with fracture theory, and highlights their universality across 2D materials.

Findings

Edge delamination causes patterned buckling at monolayer edges.

Sawtooth edge structures break symmetry and influence buckling behavior.

Delamination process aligns with fracture theory predictions.

Abstract

Delamination of thin films from the supportive substrates is critical issues in thin film industry and technology. The emergent two-dimensional materials, atomic layered materials, such as transition metal dichalcogenides are highly flexible thus the buckles and wrinkles can be easily generated and play vital effects on the physical properties. Here we introduce one kind of patterned buckling behavior caused by the delamination from substrate initiated at the edges of the chemical vapor deposition synthesized monolayer transition metal dichalcogenides, mainly due to the thermal expansion mismatch. The atomic force microscopy and optical characterizations clearly showed the puckered structures associated with strains, whereas the transmission electron microscopy revealed the special sawtooth shaped edge structures which break the geometrical symmetry of the buckling behavior of hexagonal samples. The condition of this edge delamination is in accordance with the fracture theory. This edge delamination process and buckling upon synthesis is universal for most of the ultrathin two dimensional materials, and it is definitely noteworthy in their future applications.