Surface Restructuring of Nickel Sulfide Generates Optimally-Coordinated Active Sites for ORR Catalysis

TL;DR

This study reveals how surface restructuring of Ni3S2 creates active amorphous NiS layers with optimal Ni-S coordination for oxygen reduction, advancing understanding of metal-chalcogenide electrocatalysts.

Contribution

It demonstrates that Ni3S2 undergoes self-limiting surface restructuring forming amorphous NiS layers that enhance ORR catalysis, providing a new framework for surface chemistry analysis.

Findings

Ni3S2 forms a ~2 nm amorphous NiS surface film during catalysis.

Surface Ni-S coordination correlates with catalytic activity.

Amorphous NiS provides an optimal environment for ORR.

Abstract

First-row transition metal oxides and chalcogenides have been found to rival the performance of precious metal-based catalysts for the interconversion of water and O$_2$. The high lability of the first-row transition metal ions leads to surface dynamics under the conditions of catalysis and results in active site structures distinct from those expected by surface termination of the bulk lattice. While these surface transformations have been well-characterized on many metal oxides, the surface dynamics of heavier chalcogenides under electrocatalytic conditions are largely unknown. We recently reported that the heazlewoodite Ni$_3$S$_2$ bulk phase supports efficient ORR catalysis under benign aqueous conditions and exhibits excellent tolerance to electrolyte anions such as phosphate which poison Pt. Herein, we combine electrochemistry, surface spectroscopy and high resolution microscopy to characterize the surface dynamics of Ni$_3$S$_2$ under ORR catalytic conditions. We show that Ni$_3$S$_2$ undergoes self-limiting oxidative surface restructuring to form an approximately 2 nm amorphous surface film conformally coating the Ni$_3$S$_2$ crystallites. The surface film has a nominal NiS stoichiometry and is highly active for ORR catalysis. Using DFT calculations we show that, to a first approximation, the catalytic activity of nickel sulfides is determined by the Ni-S coordination numbers at surface exposed sites through a simple geometric descriptor. In particular, we find that the surface sites formed dynamically on the surface of amorphous NiS during surface restructuring provide an optimal energetic landscape for ORR catalysis. This work provides a systematic framework for characterizing the rich surface chemistry of metal-chalcogenides and provides principles for developing a broader understanding of electrocatalysis mediated by amorphous materials.

Full text

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