The validity of 21 cm spin temperature as a kinetic temperature indicator in atomic and molecular gas
Gargi Shaw, G. J. Ferland, I. Hubeny

TL;DR
This paper investigates whether the 21 cm spin temperature reliably indicates the gas kinetic temperature in various interstellar environments, considering complex physical processes like Lyman alpha interactions.
Contribution
It provides a detailed analysis of the physical processes affecting 21 cm line populations and evaluates the conditions under which the spin temperature reflects the kinetic temperature.
Findings
21 cm spin temperature often does not trace $T_K$ due to Lyman alpha effects.
The spectral simulation code Cloudy models these processes effectively.
Lyman alpha excitation temperature rarely matches the gas kinetic temperature.
Abstract
The gas kinetic temperature () of various interstellar environments is often inferred from observations that can deduce level populations of atoms, ions, or molecules using spectral line observations; H I 21 cm is perhaps the most widely used with a long history. Usually the H I 21 cm line is assumed to be in thermal equilibrium and the populations are given by the Boltzmann distribution. A variety of processes, many involving Lyman alpha (), can affect the 21 cm line. Here we show how this is treated in the spectral simulation code Cloudy, and present numerical simulations of environments where this temperature indicator is used, with a detailed treatment of the physical processes that determine level populations within . We discuss situations where this temperature indicator traces , cases where they fail, as well as the effects of pumping on the 21…
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