Flexible and Actuating Nanoporous Poly(ionic liquids)- paper based Hybrid Membranes

TL;DR

This paper presents a simple method to create flexible, porous, and actuating membranes from poly(ionic liquids) and tissue paper, capable of solvent sensing and actuation, with potential applications in smart textiles.

Contribution

It introduces a scalable, facile fabrication technique for gradient porous, flexible membranes combining poly(ionic liquids) and tissue paper, enabling shape recovery and solvent sensing functionalities.

Findings

Membranes bend in response to organic solvents and recover shape in air.

Enhanced mechanical properties due to tissue paper incorporation.

Potential use as responsive textiles and contractile actuators.

Abstract

Porous and flexible actuating materials are important in the development of smart systems. We report here a facile method to prepare scalable, flexible actuating porous membranes based on a poly(ionic liquid)-modified tissue paper. The targeted membrane property profile was based on a synergy of a gradient porous structure of poly(ionic liquid) network and the flexibility of tissue paper. The gradient porous structure was built up through ammonia-triggered electrostatic complexation of a poly(ionic liquid) with poly(acrylic acid) (PAA) that were previously impregnated inside the tissue paper. As a result, these porous membranes undergo bending deformation in response to organic solvents in vapor or liquid phase and can recover their shape back in air, which was demonstrated to be able to serve as solvent sensors. Besides, they show enhanced mechanical properties due to the introduction of mechanically flexible tissue paper that allows the membranes to be designed as new responsive textiles and contractile actuators.