# Double-Ionization Satellites in the X-ray Emission Spectrum of Ni Metal

## TL;DR

This study measures and analyzes the X-ray emission spectrum of nickel metal, focusing on double-ionization satellites, using a laboratory spectrometer to accurately align spectra and determine satellite branching ratios.

## Contribution

It introduces a precise laboratory-based method for aligning XES and absorption spectra, enabling accurate measurement of satellite branching ratios in Ni metal.

## Key findings

- Good agreement with prior experimental results
- Consistent with theoretical multi-configuration Dirac-Fock calculations
- Accurate correction of absorption effects in X-ray spectra

## Abstract

We report measurements of the nonresonant x-ray emission spectroscopy (XES) from Ni metal in an energy range spanning the K_beta, valence-to-core, and double-ionization (DI) satellites that appear beyond the single-particle Fermi level. We make special use of a laboratory-based x-ray spectrometer capable of both x-ray emission and x-ray absorption measurements to accurately align the XES and x-ray absorption spectra to a common energy scale. The careful alignment of energy scales is requisite for correction of the strong sample absorption of DI fluorescence above the Ni K-edge energy. The successful correction of absorption effects allows a determination of the branching ratios for the [1s3d], [1s3p], [1s2p] and [1s2s] satellites with respect to their corresponding diagram lines. We compare our results with other work, finding good agreement with prior experiments and with theoretical calculations in the multi-configuration Dirac-Fock framework.

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Source: https://tomesphere.com/paper/1705.07326