Photoresponse of Natural van der Waals Heterostructures

TL;DR

This study investigates the optoelectronic properties of naturally occurring van der Waals heterostructure franckeite, revealing its potential for nanoscale optoelectronic devices due to its narrow band gap and fast photoresponse.

Contribution

First experimental analysis of the optoelectronic behavior of natural vdW heterostructure franckeite, including its band gap, photoresponse, and trap states.

Findings

Franckeite acts as a narrow band gap semiconductor with a ~1500 nm band edge.

Device exhibits high external quantum efficiency (~3%) at room temperature.

Fast photoresponse with a rise time of ~1 ms.

Abstract

Van der Waals (vdW) heterostructures consisting of two dimensional materials offer a platform to obtain material by design and are very attractive owing to novel electronic states. Research on 2D van der Waals heterostructures (vdWH) has so far been focused on fabricating individually stacked atomically thin unary or binary crystals. Such systems include graphene (Gr), hexagonal boron nitride (h-BN) and member of the transition metal dichalcogenides family. Here we present our experimental study of the opto-electronic properties of a naturally occurring vdWH, known as Franckeite, which is a complex layered crystal composed of lead, tin, antimony, iron and sulfur. We present here that thin film franckeite (60 nm < d < 100 nm) behave as narrow band gap semiconductor demonstrating a wide band photoresponse. We have observed the band-edge transition at ~ 1500 nm (~830 meV) and high external quantum efficiency (EQE~3%) at room temperature. Laser power resolved and temperature resolved photocurrent measurements reveal that the photo-carrier generation and recombination are dominated by continuously distributed trap states within the band gap. To understand wavelength resolved photocurrent, we also calculated the optical absorption properties via density functional theory. Finally, we have shown that the device has fast photoresponse with rise time as fast as ~ 1 ms. Our study provides a fundamental understanding of the optoelectronic behavior in a complex naturally occurring vdWH and can open up the possibilities of producing new type of nanoscale optoelectronic devices with tailored properties.