Superconducting States for Semi-Dirac Fermions at Zero and Finite Magnetic Fields
Bruno Uchoa, Kangjun Seo

TL;DR
This paper investigates the unique superconducting properties of anisotropic Dirac fermions with mixed linear and parabolic dispersions, revealing highly anisotropic electromagnetic responses and the potential formation of exotic smectic flux states under magnetic fields.
Contribution
It introduces the concept of superconductivity in semi-Dirac fermions with uniaxial anisotropy and predicts novel flux domain patterns near quantum criticality.
Findings
Superconducting response is highly anisotropic near the quantum critical point.
A novel smectic flux state can form under high magnetic fields.
The study extends understanding of anisotropic Dirac fermion superconductivity.
Abstract
We address the superconducting singlet state of anisotropic Dirac fermions that disperse linearly in one direction and parabolically in the other. For systems that have uniaxial anisotropy, we show that the electromagnetic response to an external magnetic flux is extremely anisotropic near the quantum critical point of the superconducting order. In the quantum critical regime and above a critical magnetic field, we show that the superconductor may form a novel exotic smectic state, with a stripe pattern of flux domains.
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Superconducting states of Semi-Dirac Fermions at Zero and Finite
Magnetic Field
Bruno Uchoa*∗* and Kangjun Seo
Department of Physics and Astronomy, University of Oklahoma, Norman, OK 73069, USA
(March 15, 2024)
Abstract
We address the superconducting singlet state of anisotropic Dirac fermions that disperse linearly in one direction and parabolically in the other. For systems that have uniaxial anisotropy, we show that the electromagnetic response to an external magnetic flux is extremely anisotropic near the quantum critical point of the superconducting order. In the quantum critical regime and above a critical magnetic field, we show that the superconductor may form a novel exotic smetic state, with a stripe pattern of flux domains.
pacs:
74.40.Kb,74.25.-q,74.25.N
Introduction. Semi-Dirac metals form a class of two dimensional (2D) systems with chiral quasiparticles that disperse linearly in one direction and quadratically in a different direction Banarjee . In the presence of spin-orbit coupling, the zero energy crossings of the Dirac cones remain protected by space group symmetries of the crystal Young and may have a non-zero Chern number Huang ; Saha . Examples of semi-Dirac metals include a variety of systems, including VO2/TiO2 heterostructures Pardo ; Huang , and strained crystals such as graphene and black phosphorus, which can undergo a topological phase transition towards a semi-Dirac phase Montambaux ; Rodian . Semi-Dirac cones have been experimentally realized on the top layer of black phosphorus under electric field effects, which tune the system from a trivial band gap insulator to a band inverted system Kim .
In this rapid communication, we explore the properties of -wave singlet states for semi-Dirac fermions in the vicinity of a quantum critical point (QCP). We show that semi-Dirac fermion superconductors have an exotic electromagnetic response to an applied magnetic flux. Due to the anisotropy of the quasiparticles, the stiffness of the order parameter to the penetration of a magnetic flux can be highly anisotropic near the QCP. In that regime, we show that semi-Dirac metals with uniaxial anisotropy can effectively behave as type I superconductors along one direction, and as type II superconductors in the other. As a result, instead of vortices, the system may form a novel smetic state with stripes of superconducting domains intercalated by thin normal strips of magnetic flux note3-1 .
Hamiltonian. For concreteness, we start from a two-orbital model on a square lattice,
[TABLE]
where is a vector with components , and , and are effective hopping parameters, is the momentum with respect to the center of the square Brillouin zone and and are Pauli matrices in the orbital space Banarjee . The low energy Hamiltonian is described by semi-Dirac fermions around four nodal points , with
[TABLE]
describing the pair of nodes at (), where is the momentum away from the nodes (we set ), with and as momentum coordinates along the two diagonal directions () and respectively. is the mass of the quasiparticles that disperse quadratically with momentum along one direction and gives the Fermi velocity of the quasiparticles that disperse linearly along the perpendicular direction. The other two nodes at are described by the low energy Hamiltonian
[TABLE]
In both sets of pairs, opposite nodal points are related by time reversal symmetry (TRS).
The Bogoliubov-deGennes Hamiltonian for Eq. (1) is
[TABLE]
where the matrix gives superconducting order parameter matrix elements in the orbital space and is the TRS operation of the Hamiltonian.
In the singlet state, there are two possible pairing channels. The first one is the intra-orbital pairing state, with pairing matrix elements , which result in a fully gapped low energy spectrum
[TABLE]
with (the valley indexes are omitted). The second channel is the inter-orbital pairing state, , which leads to gapless superconductivity, with indexing two additional branches, shown in Fig. 1b. For a given attractive interaction, the fully gapped state lowers the free energy of the system more than the gapless one by pushing the energy states down towards the bottom of the band, as shown in Fig. 1a. In this letter, we will focus on the dominant instability and address the thermodynamic and electromagnetic properties of the fully gapped state.
Critical behavior. The free energy of the superconducting state is , with indexing the particle and hole branches of the spectrum respectively, is the temperature and is the effective attractive interaction that leads to formation of Cooper pairs. In mean field, minimization of the free energy with respect to (assumed to be real) gives the standard BCS equation of state Using the parametrization where and , with , the density of states can be written in terms of the Jacobian of the transformation Adroguer ,
[TABLE]
Integration in gives the actual density of states, , where , with an elliptic function and is the node degeneracy.
At zero temperature and half filling, the phase transition is quantum critical due to the vanishing DOS at the nodal point Kotov ; Uchoa ; Zhao . Near the QCP, the mean field zero temperature gap scales with the coupling as
[TABLE]
where , with a gamma function, and is the critical coupling defined in terms of the effective energy bandwidth . In the gapless state, the critical coupling is , and hence the gapped instability clearly prevails. In the two band model (1) where , and , then . In the limit where , the critical coupling can be small enough to allow the QCP physics to be accessed experimentally. In general, since scales with the velocity and mass of the quasiparticles, the critical coupling can be further lowered with strain effects Wei .
The mean field critical temperature is given by as shown in Fig. 2. In the critical regime,
[TABLE]
The specific heat at fixed volume is defined as At the phase transition, the specific heat jump normalized by specific heat in the normal side of the transition, deltaC . In the case of Dirac fermions in 2D (graphene), uchoa , while in the Fermi liquid case Tinkham .
Supercurrent. To calculate the Meissner response to an external magnetic flux, we include a vector potential in Hamiltonian (4) in the Coulomb gauge, explicitly breaking TRS, . When the Fermi level is at the neutrality point, the energy spectrum can be calculated analytically,
[TABLE]
with , and , with , where describe the symmetric () and anti-symmetric () combinations in the vector potential, respectively.
The calculation of the supercurrent from Eq. (1) and (4) can be done in a very general way for any arbitrary vector defined in terms of generic functions of momenta , provided TRS is preserved at zero field. From the minimal coupling between currents and electromagnetic fields, , the current operator is . The supercurrent in the London limit is where is the Green’s function.
In leading order in the vector potential, the diamagnetic response in the Coulomb gauge is given by where is the London kernel. For anisotropic superconductors that preserve inversion symmetry, the kernel has the form , with a unitary vector SM . The off-diagonal components of the Kernel result from phase modes Millis , which ensure that the static continuity equation is satisfied in the Coulomb gauge. Alternatively, we can simply fix the gauge in such a way that . After a proper regularization of the deep energy states at the bottom of the band Uchoa3 , what is done by imposing periodic boundary conditions at the edge of the Brillouin zone SM , the London kernel per node is
[TABLE]
restoring . Although is calculated in a fixed gauge, gauge invariance is restored by screening effects note , which preserve the transversality condition of the supercurrent,** **, irrespective of the gauge choice Pines .
In the semi-Dirac case, the supercurrent due to each node is anisotropic, as expected, with
[TABLE]
and
[TABLE]
where , with . This integral can be analytically calculated in the zero temperature limit and close to the critical temperature,
[TABLE]
where , and
[TABLE]
with .
Near the critical temperature, the kernel anisotropy scales linearly with and vanishes at the QCP. In the zero temperature limit, and hence the anisotropy lineraly with the gap as one approaches the QCP at (orange line in Fig 3). In that limit, the system is extremely anisotropic note 2 , with relativistic quasiparticles carrying a supercurrent along the direction of linear dispersion. In Fig. 3, we show the plot of the anisotropy per node versus the gap for fixed temperatures . When , the kernel has a crossover from the anomalous zero temperature scaling regime, , , to the standard BCS scaling, , where the anisotropy saturates to a constant.
*Quantum fluctuations*Allowing the condensate to flow with momentum , we expand the free energy at zero temperature in powers of the order parameter and . The Ginzburg-Landau (GL) free energy, which fully includes fluctuation effects, is
[TABLE]
where gives the order parameter around the saddle point solution in Eq. (7), , , and .
At finite magnetic field, ** by **a suitable gauge choice. Near the QCP, the GL supercurrent independently recovers Eq. (11) and (12) at . Hence, the anisotropic quantum critical scaling of the London kernel with , namely and , persists near the QCP, where quantum fluctuations dominate.
Because the free energy (15) has non-analytic terms both in the kinetic energy and in the interaction term , one cannot expand in the fluctuation fields in order to integrate them out and calculate the quantum fluctuation corrections to the scaling of , with in mean field note3 . Instead, one needs to resort to field theoretical methods Vojta ; Khveschenko , which are beyond the scope of this work and will be addressed elsewhere. In any case, the mean field analysis is accurate in the regime where the quadratic term of (15) dominates over the interaction term , namely .
Penetration depth. For a thin film of thickness , the penetration depth is given by the London kernel, with . In general, for systems of semi-Dirac fermions with uniaxial anisotropy, such as in uniaxially strained graphene or semi-metallic black phosphorus, the total London kernel is calculated from the Meissner response of a single nodal point times the nodal degeneracy . In that case, at zero temperature,
[TABLE]
and
[TABLE]
and hence the penetration depth along the and axes grows near the QCP with different scaling exponents, and . Near the critical temperature, the penetration depth is still anisotropic, but follows the standard BCS temperature scaling .
Coherence length. In the zero temperature limit, the coherence length corresponds to the length scale where the energy of the system changes by an amount set by the mass gap . Near the neutrality point (, with the chemical potential away from half filling), the corresponding change in the momentum domain satisfies . Since , variations along the direction where the energy spectrum is linear imply that . A similar dimensional analysis along the direction of parabolic dispersion gives , and hence
[TABLE]
in contrast with the standard Fermi liquid result (), where , with the Fermi velocity Tinkham . Fluctuation effects are expected to give small deviations in the quantum critical scaling of the coherence length with due to the emergence of an anomalous dimension.
In mean field, the ratio between the penetration depth in the London limit and the coherence length is given by
[TABLE]
and
[TABLE]
along the two principal directions and , with proportionality factors of the order of 1. Therefore, in the vicinity of the QCP, the order parameter becomes rigid for amplitude variations along the direction where the quasiparticles have linear dispersion (), as in type superconductors. At the same time, the order parameter becomes soft for variations along the direction of parabolic dispersion (), as in type II superconductors. While fluctuations could provide corrections to the scaling of , the mean field analysis is suggestive of a possible smetic instability near the QCP.
*Stripe phase.*The energy of a domain wall becomes negative when . Near the QCP, the magnetic flux can form a stripe pattern of domain walls oriented along the direction, which coincides with the “easy” direction for the supercurrent as indicated in Fig. 4a. Those domains separate superconducting regions (S), which are screened by diamagnetic currents (red arrows in Fig. 4a), from normal regions (N) of width separated by a distance . Because the magnetic field has a stiffness of the order of the penetration depth along the direction, those domain walls of magnetic flux repel each other and can stabilize a stripe phase in the regime where the magnetic field normal to the sample is strong enough.
Domain wall formation in the bulk of macroscopic samples is ellusive and has been observed only in a few ferromagnetic superconductors Goldstein ; Prozorov ; Wang . For samples with finite slab geometry, domain walls are observed in the intermediate state of type I superconductors, where the period of the laminar state is set by the thickness of the sample, . In semi-Dirac metals with uniaxial anisotropy, the stripe phase will have lower energy compared to the vortex state of type II superconductors near the QCP. In the presence of magnetic fields, the Gibbs free energy of a striped normal domain surrounded by superconducting regions of width is DeGennes
[TABLE]
where is the distance between the normal domain walls normalized by the penetration depth and is the field that corresponds to the condensation energy . The equilibrium separation between the stripes follows trivially from minimization of the free energy for fixed field, .
In Fig. 4b, we show the scaling of as a function of the magnetic field . Below the critical field , , and the system has a uniform phase (Meissner state). In the regime , is finite and the system will form a smetic state with stripes of superconducting domains separated by thin strips of magnetic flux. Eventually, when , the separation of the domains DeGennes and superconductivity will be destroyed.
*Conclusions. *In summary, we examined the critical properties of semi-Dirac metal superconductors at zero and finite magnetic fields. We showed that near the quantum critical regime and at finite fields, the anisotropy of the quasiparticles leads to an exotic electromagnetic response which may stabilize a novel smetic state of superconducting stripes.
Acknowledgements. BU thanks K. Mullen, M. Fogler and S. Parmeswaran for helpful discussions. BU acknowledges NSF CAREER grant DMR-1352604 for support.
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