Lightning Chemistry on Earth-like Exoplanets

TL;DR

This paper introduces a comprehensive lightning-induced atmospheric chemistry model applicable to Earth-like exoplanets, predicting chemical yields and spectral features, and assessing detectability with current telescopes.

Contribution

The study develops a coupled hydrodynamics and kinetic chemistry model for lightning on exoplanets, providing new predictions for atmospheric composition changes and spectral signatures.

Findings

NO and NO2 yields match observations for Earth analogues

Lightning can significantly alter atmospheric composition, including O3 and C2N

Spectral features of lightning-induced chemicals are below JWST detection limits

Abstract

We present a model for lightning shock induced chemistry that can be applied to atmospheres of arbitrary H/C/N/O chemistry, hence for extrasolar planets and brown dwarfs. The model couples hydrodynamics and the STAND2015 kinetic gas-phase chemistry. For an exoplanet analogue to the contemporary Earth, our model predicts NO and NO2 yields in agreement with observation. We predict height-dependent mixing ratios during a storm soon after a lightning shock of NO ~ 1e-3 at 40 km and NO2 ~ 1e-4 below 40 km, with O3 reduced to trace quantities (<< 1e-10). For an Earth-like exoplanet with a CO2/N2 dominated atmosphere and with an extremely intense lightning storm over its entire surface, we predict significant changes in the amount of NO, NO2, O3, H2O, H2, and predict significant abundance of C2N. We find that, for the Early Earth, O2 is formed in large quantities by lightning but is rapidly processed by the photochemistry, consistent with previous work on lightning. The effect of persistent global lightning storms are predicted to be significant, primarily due to NO2, with the largest spectral features present at ~3.4 {\mu}m and ~6.2 {\mu}m. The features within the transmission spectrum are on the order of 1 ppm and therefore are not likely detectable with JWST. Depending on its spectral properties, C2N could be a key tracer for lightning on Earth-like exoplanets with a N2/CO2 bulk atmosphere, unless destroyed by yet unknown chemical reactions.

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