# Dislocation-free axial InAs-on-GaAs nanowires on silicon

## TL;DR

This paper demonstrates the successful growth of dislocation-free axial InAs-on-GaAs nanowires on silicon, achieving high yield and strain management in heterostructures with significant lattice mismatch.

## Contribution

Developed a two-step growth process for high-yield, dislocation-free InAs-on-GaAs nanowires on silicon with detailed structural and compositional analysis.

## Key findings

- Achieved 90% yield of straight nanowires
- Confirmed dislocation-free interfaces via strain mapping
- InAs segment composition is In₀.₈₅Ga₀.₁₅As with 6% lattice mismatch

## Abstract

We report on the growth of axial InAs-on-GaAs nanowire heterostructures on silicon by molecular beam epitaxy using 20 nm diameter Au catalysts. First, the growth parameters of the GaAs nanowire segment were optimized to achieve a pure wurtzite crystal structure. Then, we developed a two-step growth procedure to enhance the yield of vertical InAs-on-GaAs nanowires. We achieved 90% of straight InAs-on-GaAs nanowires by further optimizing the growth parameters. We investigated the composition change at the interface by energy dispersive X-ray spectroscopy and the nanowire crystal structure by transmission electron microscopy. The nominal composition of the InAs segment is found to be In$_{x}$Ga$_{1-x}$As with $x$=0.85 and corresponds to 6% of lattice mismatch with GaAs. Strain mapping performed by the geometrical phase analysis of high-resolution images revealed a dislocation-free GaAs/InAs interface. In conclusion, we successfully fabricated highly mismatched heterostructures, confirming the prediction that axial GaAs/InAs interfaces are pseudomorphic in nanowires below 40 nm diameter.

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Source: https://tomesphere.com/paper/1704.05631