Ultrafast Triplet Pair Formation and Subsequent Thermally Activated Dissociation Control Efficient Endothermic Singlet Exciton Fission

TL;DR

This study reveals ultrafast triplet pair formation and thermally activated dissociation in singlet exciton fission, demonstrating efficient, temperature-independent initial processes and slower morphology-dependent separation, advancing photovoltaic efficiency understanding.

Contribution

The paper provides a detailed temporal and mechanistic understanding of triplet pair formation and dissociation in TIPS-tetracene, highlighting the role of electronic-vibrational coupling and morphology.

Findings

Triplet pair formation occurs within 300 fs.

Triplet pair dissociation happens over 10-100 ns.

Process is mediated by electronic and vibrational coupling.

Abstract

Singlet exciton fission (SF), the conversion of one spin-singlet exciton (S1) into two spin-triplet excitons (T1), could provide a means to overcome the Shockley-Queisser limit in photovoltaics. SF as measured by the decay of S1 has been shown to occur efficiently and independently of temperature even when the energy of S1 is as much as 200 meV less than 2T1. Here, we study films of TIPS-tetracene using transient optical spectroscopy and show that the initial rise of the triplet pair state (TT) occurs in 300 fs, matched by rapid loss of S1 stimulated emission, and that this process is mediated by the strong coupling of electronic and vibrational degrees of freedom. This is followed by a slower 10 ps morphology-dependent phase of S1 decay and TT growth. We observe the TT to be thermally dissociated on 10-100 ns timescales to form free triplets. This provides a model for "temperature independent", efficient TT formation and thermally activated TT separation.