Electron-polaron--electron-polaron bound states in mass-gap graphene-like planar quantum electrodynamics: $s$-wave bipolarons
O.M. Del Cima, E.S. Miranda

TL;DR
This paper investigates the formation of bound states called bipolarons in a Lorentz-invariant, mass-gap graphene-like quantum electrodynamics model, highlighting attractive interactions leading to quasiparticle pairing.
Contribution
It introduces a Lorentz-invariant model of mass-gap graphene-like QED$_3$ and demonstrates the existence of $s$-wave bipolarons due to attractive electron-polaron interactions.
Findings
Attractive interactions in low-energy scattering favor bipolaron formation.
The model predicts stable $s$-wave bipolarons in the system.
Lorentz invariance is maintained in the mass-gap QED$_3$ framework.
Abstract
A Lorentz invariant version of a mass-gap graphene-like planar quantum electrodynamics, the parity-preserving massive QED, exhibits attractive interaction in low-energy electron-polaron--electron-polaron -wave scattering, favoring quasiparticles bound states, the -wave bipolarons.
| state |
wave
function |
electric charge | chiral charge | spin | quasiparticle |
|---|---|---|---|---|---|
| electron polaron | |||||
| electron polaron | |||||
| hole polaron | |||||
| hole polaron |
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Electron-polaron–electron-polaron bound states in mass-gap graphene-like planar quantum electrodynamics: -wave bipolarons
O.M. Del Cima
Universidade Federal de Viçosa (UFV),
Departamento de Física - Campus Universitário,
Avenida Peter Henry Rolfs s/n - 36570-900 - Viçosa - MG - Brazil.
E.S. Miranda
Universidade Federal de Viçosa (UFV),
Departamento de Física - Campus Universitário,
Avenida Peter Henry Rolfs s/n - 36570-900 - Viçosa - MG - Brazil.
Abstract
A Lorentz invariant version of a mass-gap graphene-like planar quantum electrodynamics, the parity-preserving massive QED3, exhibits attractive interaction in low-energy electron-polaron–electron-polaron -wave scattering, favoring quasiparticles bound states, the -wave bipolarons.
pacs:
11.10.Kk 11.15.-q 11.80.-m 71.10.Pm 71.38.Mx
I Introduction
The seminal works by Deser, Jackiw, Templeton and Schonfeld deser-jackiw-templeton-schonfeld have attracted attention to the quantum electrodynamics in three space-time dimensions (QED3) in view of its potentiality as theoretical foundation for quasi-planar condensed matter phenomena, such as high- superconductors high-Tc , quantum Hall effect quantum-hall-effect , topological insulators topological-insulators , topological superconductors topological-superconductors and graphene graphene . Since then, the planar quantum electrodynamics has been widely studied in many physical configurations, namely, small (perturbative) and large (non perturbative) gauge transformations, Abelian and non-Abelian gauge groups, fermions families, odd and even under parity, compact space-times, space-times with boundaries, curved space-times, discrete (lattice) space-times, external fields and finite temperatures.
The pure graphene graphene monolayer is a gapless (massless gap graphene) bidimensional system which behaves like a half-filling semimetal with its charge carriers (quasiparticles) being described by massless charged Dirac fermions. However, for practical applications like transistors a gap (mass-gap) graphene mass-gap-graphene is more appropriate, and such a mass-gap effect is observed in pure monolayer graphene on substrates hagues . Electron-electron interactions (electron pairing) in graphene electron-pairing include electron polarons (electron-phonon) electron-phonon scattering processes polarons , where this quasiparticle, the polaron, which is formed by a bound state of electron (or hole) and phonon, was first introduced by Landau landau .
The proposed issue in this work about the possibility of -wave bipolarons emerging from the parity-preserving massive QED3 – a mass-gap graphene-like mass-gap-graphene planar quantum electrodynamics – is presented as follows. Initially, the model defined by its discrete and continuous symmetries is introduced and, since the interactions are nonconfining – the vector mesons, the photon and the Néel quasiparticle, are massive – the asymptotic states for the fermions (electron polarons) are established. Hereafter, in the low-energy limit, the - and -wave Møller (-polaron–-polaron) scattering amplitudes are computed and their respective interaction potentials obtained and analysed. However, from this analysis, it was found conditions on the parameters which, in spite of the -wave scattering potential still remains repulsive, the -wave interaction potential becomes attractive. The latter shall favour -polaron–-polaron bound states – provided the attractive -wave scattering potential satisfies necessary conditions chadan-khuri-martin-wu ; kato ; newton-seto ; bargmann – giving rise to the -wave bipolarons condensates polarons .
II The model
The Lorentz invariant version of mass-gap graphene-like planar quantum electrodynamics, the parity-even massive QED3, is defined by the action:
[TABLE]
where {\hbox to0.0pt{\hbox{\mskip 4.0mu/}\hss}D}\psi_{\pm}\equiv(\hbox to0.0pt{\hbox{\mskip 1.0mu/}\hss}\partial+ie\hbox to0.0pt{\hbox{\mskip 3.0mu/}\hss}A\pm ig\hbox to0.0pt{\hbox{\mskip 1.0mu/}\hss}a)\psi_{\pm}, and any object {\hbox to0.0pt{\hbox{\mskip 4.0mu/}\hss}X}\equiv X^{\mu}\gamma_{\mu}. The coupling constants and are dimensionful, with mass dimension , and, and are mass parameters with mass dimension . Also, and , are the field strengths associated to the electromagnetic field () and the Néel gauge field (), respectively, and are two kinds of fermions – each of them describing electron polarons (electron-phonon) and hole polarons (hole-phonon) quasiparticles – where the subscripts are related to their spin sign binegar , and the gamma matrices are .
II.1 The symmetries: parity and
The CPT-even action (1) is invariant under:
parity symmetry ():
[TABLE] 2. 2.
gauge symmetry ():
[TABLE]
II.2 The spectrum: degrees of freedom, spin, masses and charges
The free Dirac equations associated to and , which stem from the action (1), read:
[TABLE]
So, by expanding the operators and in terms of the -number plane wave solutions of the Dirac equations, with operator-valued amplitudes, , , and (annihilation operators), and , , and (creation operators):
[TABLE]
where . Consequently, from (4) and (5)-(6), by assuming , the wave functions, , , and , are given by:
[TABLE]
satisfying the following conditions:
[TABLE]
where
[TABLE]
are the momenta space solutions of the Dirac equations at the particle rest-frame, . The microcausality conditions for and :
[TABLE]
together with the Dirac equations (4) and the normalization conditions (9)-(10), implies that:
[TABLE]
where all other anticommutators vanish and, for the vacuum state , .
The quantum operators associated to space-time () symmetry and internal () symmetry, spin (), electric charge () and Néel (chiral) charge (), are
[TABLE]
respectively, with their action upon the asymptotic fermion (antifermion) states with spin up and spin down, () and ():
[TABLE]
where
[TABLE]
which means that, () creates a spin-up (spin-down) fermion (electron polaron) and () creates a spin-down (spin-up) antifermion (hole polaron). Moreover, from the results above, for any fermion or antifermion (spin up or down) quantum state , it is verified that
[TABLE]
which proves the correlation among spin and chiral charge (see TABLE 1).
In the low-energy limit (Born approximation), the two-particle scattering potential is given by the Fourier transform of the two-particle -channel scattering amplitude (direct scattering) sakurai . However, so as to compute the scattering amplitudes, use has been made of the propagators. Hence, switching off the coupling constants ( and ), the tree-level propagators in momenta space, for all the fields, read:
[TABLE]
From the propagators above, , , , and , the spectrum and the tree-level unitarity of the model can be be analyzed by coupling them to external currents, , compatible with the symmetries of the model, where the current-current transition amplitudes in momentum space are written as: . Then, by taking the imaginary part of the residues of the current-current amplitudes, , at the poles, it can be probed the necessary conditions for unitarity – positive imaginary part of the residues of the transition amplitudes, , as a consequence of the -matrix be unitary – at the tree-level and the counting of the degrees of freedom described by the fields, . In summary, it has been concluded del_cima-miranda that the two kind of fermions, and , hold two massive degrees of freedom with mass – the electron-polaron () and the hole-polaron () associated to the spinor , and the electron-polaron () and the hole-polaron () associated to the spinor . Also, the vector fields, the electromagnetic field () and the Néel gauge field (), carry each one two massive degrees of freedom with mass , moreover, it shall be noticed that the single massless mode in model, displayed in , does not propagate, it decouples. From the results presented above, it can be concluded that the the parity-preserving massive QED3 is free from tachyons and ghosts at the classical level. Nevertheless, to have full control of the unitarity at tree-level, it is still necessary to study the behaviour of the scattering cross sections in the limit of high center of mass energies, by analyzing the Froissart-Martin bound froissart-martin-bound .
III The Møller scattering
In order to calculate the scattering amplitudes, it remains the vertex Feynman rules associated to the interaction vertices -e{\overline{\psi}_{\pm}}\hbox to0.0pt{\hbox{\mskip 3.0mu/}\hss}A\psi_{\pm} and \mp g{\overline{\psi}_{\pm}}\hbox to0.0pt{\hbox{\mskip 1.0mu/}\hss}a\psi_{\pm}: and , respectively.
The -channel -polaron–-polaron Møller scattering amplitudes mediated by the electromagnetic and the Néel quanta (see FIG. 1) are given by:
[TABLE]
Furthermore, in the center of mass (CM) reference frame, the three-momenta configuration of the two scattered fermions, , , and , so as the momentum transfer, , are fixed as
[TABLE]
where is the CM scattering angle, defined as the angle among the directions in the CM frame of the two incoming (initial state) and outgoing (final state) fermions.
The total - and -wave Møller scattering amplitudes can now be derived from the partial ones (35)-(38) in the low-energy approximation, () and ( or ), where, by assuming the momenta configuration above (39)-(41), it follows that:
[TABLE]
III.1 Scattering potentials
In the low-energy (nonrelativistic) limit, the two-particle interaction potential, in the Born approximation, is nothing but the two-dimensional Fourier transform of the lowest-order two-particle scattering amplitude:
[TABLE]
Accordingly to the Born approximation (44), the electron-polaron–electron-polaron - and -wave scattering potentials, mediated by the photon and the Néel quasiparticle, read:
[TABLE]
Thereafter, it can be concluded from (46) that, regardless the values of the electromagnetic and the chiral coupling constants – and , respectively – the -polaron–-polaron interaction in -wave state ( or ) is always repulsive. Nevertheless, from (45), it shall be stressed about the possibility of attractive -polaron–-polaron interaction in -wave state () provided . In this case, where , the -wave interaction potential is attractive,
[TABLE]
however, this is not a sufficient condition for the existence of bound states.
III.2 Bound states
Beyond the attractive nature, provided that , of -wave interaction potential (47) it has to be weak in the sense of Kato kato ,
[TABLE]
so as to satisfy the Newton-Setô and the Bargmann bounds newton-seto ; bargmann , which guarantee bound states and establish an upper bound for their number () for vanishing angular momentum ():
[TABLE]
and upper bound for their number () for nonvanishing angular momentum ():
[TABLE]
respectively, where and is the -polaron–-polaron reduced mass.
It has been proved elsewhere del_cima-franco-lima that, whenever an interaction potential of the type is attractive (), it satisfies the following criteria: the weakness in the sense of Kato (48); the Newton-Setô bound (49) for ; and the Bargmann bound (50) for all such that (where is the floor function of ). In the same manner, by means of the effective potential with , it can be figured out that bound states arise (see FIG. 2). In addition to, it shall be stressed that these fulfilled conditions, (48), (49) and (50), guarantee the existence of bound states for any kind of three-dimensional space-time model which exhibits scattering potential of the type ().
IV Conclusions
The Lorentz invariant parity-preserving massive QED3, a mass-gap graphene-like planar quantum electrodynamics model, at low-energy limit exhibits electron-polaron–electron-polaron scattering short range non confining potentials, similarly it can be concluded that the same behaviour takes place for hole-polaron–hole-polaron scatterings. The interactions among electron-polarons and hole-polarons are mediated by two massive vector mesons, the photon (electric charge source) and the Néel quasiparticle (chiral charge source), both stemming from the gauge symmetry. It should be noticed that it was disclosed the correlation among the electron-polaron (hole-polaron) spin polarization and correspondent chiral charge. At the tree-level, the absence of tachyons () and ghosts () in the model spectrum guarantees causality and unitarity, respectively, at this level. Notwithstanding, in order to complete the tree-level unitarity analysis, it remains to finish the proof that the scattering cross sections in the limit of high center of mass energies respect the Froissart-Martin bound froissart-martin-bound , but since ultraviolet problems are less critical in lower dimensional quantum field models, together with the fact that the four space-time dimensional QED (QED4) sakurai satisfies the Froissart-Martin bound, consequently this fulfilment shall be foreseen for parity-even massive QED3. Also, it shall be pointed out that for condensed matter systems like graphene, the quasiparticles (electron-polaron and hole-polaron) dynamics is in non relativistic regime, so ultraviolet unitarity upper bound violations should not be expected.
Bearing in mind hypothetical applications of the model presented here to graphene, or any other two dimensional system, the orders of magnitude of some theoretical parameters need to be established firstly, namely, a typical mass-gap in graphene is around meV mass-gap-graphene whereas the low-energy limit for a condensed matter system is of eV order. In addition to that, the characteristic range of the two interactions, mediated by the both massive photon and the Néel quantum, shall be associated to the pair-coherence length measured in graphene, orders of magnitude in nm pair-coherence-length . The mass-gap in graphene mass-gap-graphene , besides of being more realistic, can be either achieved when pure graphene monolayer is settled on substrates hagues , increasing its application range and improving device developments.
At the low-energy limit, the non relativistic electron-polaron–electron-polaron (or hole-polaron–hole-polaron) scattering potential, owing to photon and Néel quasiparticle short range exchanges, shows to be always repulsive (46) for parallel (-wave) electron-polaron (hole-polaron) spin polarizations (+ or +). Nevertheless, for electron-polaron–electron-polaron (or hole-polaron–hole-polaron) scatterings with antiparallel (-wave) spin polarizations (+), the -wave interaction potential (47) might be attractive provided ()-polaron–Néel-quasiparticle coupling strength () be stronger than the strength of ()-polaron–photon coupling (), . Moreover, the -wave attractive scattering potential (47) satisfies the Kato condition kato , the Newton-Setô and the Bargmann upper bounds newton-seto ; bargmann , indicating that -wave bipolarons polarons might stem from these electron-polaron–electron-polaron quasiparticles bound states del_cima-franco-lima . The possible emergence of such a Cooper-type -polaron–-polaron condensate (bipolaron) directly calls the issue of superconductivity in graphene graphene-superconductor , thus a deep investigation on that deserves special attention.
Acknowledgments
The authors thank O. Piguet, J.A. Helayël-Neto, D.H.T. Franco and J.M. Fonseca, as well as to the anonymous referee for helpful comments and suggestions. Special thanks are due to L.G. Rizzi. O.M.D.C. dedicates this work to his father (Oswaldo Del Cima, in memoriam), mother (Victoria M. Del Cima, in memoriam), daughter (Vittoria) and son (Enzo). CAPES-Brazil is acknowledged for invaluable financial help.
Author contribution statement
All authors have been contributed equally.
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