Optimal strengthening of particle-loaded liquid foams

TL;DR

This study investigates the rheological properties of particle-loaded liquid foams, revealing a new elastic regime driven by a granular skeleton structure and providing models to predict their elastic modulus based on microstructure.

Contribution

It introduces a novel elastic regime in particle-loaded foams and links the microstructure to rheological behavior, expanding understanding of foam mechanics with granular skeleton insights.

Findings

Identification of a new elastic regime with high modulus values

Granular skeleton formation responsible for elastic behavior

Two-step yielding process observed in rheological tests

Abstract

Foams made of complex fluids such as particle suspensions have a great potential for the development of advanced aerated materials. In this paper we study the rheological behavior of liquid foams loaded with granular suspensions. We focus on the effect of small particles, i.e. particle-to-bubble size ratio smaller than 0.1, and we measure the complex modulus as a function of particle size and particle volume fraction. With respect to previous work, the results highlight a new elastic regime characterized by unequaled modulus values as well as independence of size ratio. A careful investigation of the material microstructure reveals that particles organize through the network between the gas bubbles and form a granular skeleton structure with tightly packed particles. The latter is proven to be responsible for the reported new elastic regime. Rheological probing performed by strain sweep reveals a two-step yielding of the material: the first one occurs at small strain and is clearly attributed to yielding of the granular skeleton; the second one corresponds to the yielding of the bubble assembly, as observed for particle-free foams. Moreover the elastic modulus measured at small strain is quantitatively described by models for solid foams in assuming that the granular skeleton possesses a bulk elastic modulus of order 100 kPa. Additional rheology experiments performed on the bulk granular material indicate that this surprisingly high value can be understood as soon as the magnitude of the confinement pressure exerted by foam bubbles on packed grains is considered.