# Various arsenic network structures in 112-type Ca1-xLaxFe1-yPdyAs2 revealed by synchrotron x-ray diffraction experiments

## TL;DR

This study synthesizes and characterizes novel 112-type palladium-doped iron arsenides, revealing diverse arsenic network structures and providing insights into their potential as high-temperature superconductors.

## Contribution

It introduces new 112-type iron arsenide compounds with unique arsenic networks and uses synchrotron X-ray techniques to analyze their structures and oxidation states.

## Key findings

- Different arsenic network structures identified in synthesized compounds.
- Similar oxidation states around FeAs4 tetrahedra across samples.
- Potential parent compounds for high Tc 112-type superconductors suggested.

## Abstract

Two novel 112-type palladium doped iron arsenides were synthesized and identified using comprehensive studies involving synchrotron x-ray diffraction and x-ray absorption near edge structure (XANES) experiments. Whereas in-plane arsenic zigzag chains were found in 112-type superconducting iron arsenide, Ca1-xLaxFeAs2 with maximum Tc = 34 K, deformed arsenic network structures appeared in 112-type materials such as longitudinal arsenics zigzag chains in CaFe1-yPdyAs2 (y ~ 0.51) and arsenic square sheets constructed via hypervalent bonding in Ca1-xLaxFe1-yPdyAs2 (x ~ 0.31, y ~ 0.30). As K-edge XANES spectra clarified the similar oxidization states around FeAs4 tetrahedrons, expecting us the possible parents for high Tc 112-type iron arsenide superconductors.

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Source: https://tomesphere.com/paper/1703.04204