# Rheology of hydrating cement paste: crossover between two aging processes

## TL;DR

This study investigates how applied strain and temperature influence the hydration dynamics of cement paste, revealing a transition between two aging processes characterized by different rheological behaviors and an instability linked to fracture mechanics.

## Contribution

It uncovers the crossover between two distinct aging processes in cement paste rheology, highlighting the roles of density, inter-particle interactions, and an instability tunable by temperature.

## Key findings

- Initial hydration dominated by hydrodynamic lubrication with sub-linear stress-strain rate relation.
- Later stage involves frictional interactions with super-linear stress-strain rate relation.
- An instability related to fracture mechanics separates the two processes and is tunable by temperature.

## Abstract

The roles of applied strain and temperature on the hydration dynamics of cement paste are uncovered in the present study. We find that the system hardens over time through two different aging processes. The first process dominates the initial period of hydration and is characterized by the shear stress $\sigma$ varying sub-linearly with the strain-rate $\dot{\gamma}$; during this process the system is in a relatively low-density state and the inter-particle interactions are dominated by hydrodynamic lubrication. At a later stage of hydration the system evolves to a high-density state where the interactions become frictional, and $\sigma$ varies super-linearly with $\dot{\gamma}$; this is identified as the second process. An instability, indicated by a drop in $\sigma$, that is non-monotonic with $\dot{\gamma}$ and can be tuned by temperature, separates the two processes. Both from rheology and microscopy studies we establish that the observed instability is related to fracture mechanics of space-filling structure.