# Nanoscale Solid State Batteries Enabled By Thermal Atomic Layer Deposition of a Lithium Polyphosphazene Solid State Electrolyte

## TL;DR

This paper presents a novel atomic layer deposition process for creating conformal, lithium-conducting solid electrolytes in nanoscale solid state batteries, enabling high-quality, thin, flexible energy storage devices.

## Contribution

It introduces a new ALD method for LiPON-based electrolytes with high ionic conductivity and stability, suitable for ultra-thin and flexible solid state batteries.

## Key findings

- Achieved ionic conductivity of 6.51×10^{-7} S/cm at 35°C.
- Demonstrated integration into full solid state batteries with LiCoO₂ and Si.
- Fabricated and operated batteries with electrolytes thinner than 100 nm.

## Abstract

Several active areas of research in novel energy storage technologies, including three-dimensional solid state batteries and passivation coatings for reactive battery electrode components, require conformal solid state electrolytes. We describe an atomic layer deposition (ALD) process for a member of the lithium phosphorus oxynitride (LiPON) family, which is employed as a thin film lithium-conducting solid electrolyte. The reaction between lithium tert-butoxide (LiO$^t$Bu) and diethyl phosphoramidate (DEPA) produces conformal, ionically conductive thin films with a stoichiometry close to Li$_2$PO$_2$N between 250 and 300$^\circ$C. The P/N ratio of the films is always 1, indicative of a particular polymorph of LiPON which closely resembles a polyphosphazene. Films grown at 300$^\circ$C have an ionic conductivity of $6.51\:(\pm0.36)\times10^{-7}$ S/cm at 35$^\circ$C, and are functionally electrochemically stable in the window from 0 to 5.3V vs. Li/Li$^+$. We demonstrate the viability of the ALD-grown electrolyte by integrating it into full solid state batteries, including thin film devices using LiCoO$_2$ as the cathode and Si as the anode operating at up to 1 mA/cm$^2$. The high quality of the ALD growth process allows pinhole-free deposition even on rough crystalline surfaces, and we demonstrate the fabrication and operation of thin film batteries with the thinnest (<100nm) solid state electrolytes yet reported. Finally, we show an additional application of the moderate-temperature ALD process by demonstrating a flexible solid state battery fabricated on a polymer substrate.

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Source: https://tomesphere.com/paper/1702.04009