# Semiclassical Szeg\"o limit of eigenvalue clusters for the hydrogen atom Zeeman Hamiltonian

## TL;DR

This paper establishes a semiclassical eigenvalue distribution theorem for the hydrogen atom under a weak magnetic field, extending Szeg"o-type results to unbounded Zeeman perturbations and connecting quantum eigenvalues with classical Kepler orbits.

## Contribution

It introduces a Szeg"o-type limit theorem for eigenvalue clusters of the hydrogen atom with unbounded Zeeman perturbations, linking quantum spectra to classical dynamics.

## Key findings

- Derived a limit measure involving classical Kepler orbits.
- Connected eigenvalue shifts to the angular momentum component along the magnetic field.
- Extended Szeg"o-type results to unbounded differential operator perturbations.

## Abstract

We prove a limiting eigenvalue distribution theorem (LEDT) for suitably scaled eigenvalue clusters around the discrete negative eigenvalues of the hydrogen atom Hamiltonian formed by the perturbation by a weak constant magnetic field. We study the hydrogen atom Zeeman Hamiltonian $H_V(h,B) = (1/2)( - i h {\mathbf \nabla} - {\mathbf A}(h))^2 - |x|^{-1}$, defined on $L^2 (R^3)$, in a constant magnetic field ${\mathbf B}(h) = {\mathbf \nabla} \times {\mathbf A}(h)=(0,0,\epsilon(h)B)$ in the weak field limit $\epsilon(h) \rightarrow 0$ as $h\rightarrow{0}$. We consider the Planck's parameter $h$ taking values along the sequence $h=1/(N+1)$, with $N=0,1,2,\ldots$, and $N\rightarrow\infty$. We prove a semiclassical $N \rightarrow \infty$ LEDT of the Szeg\"o-type for the scaled eigenvalue shifts and obtain both ({\bf i}) an expression involving the regularized classical Kepler orbits with energy $E=-1/2$ and ({\bf ii}) a weak limit measure that involves the component $\ell_3$ of the angular momentum vector in the direction of the magnetic field. This LEDT extends results of Szeg\"o-type for eigenvalue clusters for bounded perturbations of the hydrogen atom to the Zeeman effect. The new aspect of this work is that the perturbation involves the unbounded, first-order, partial differential operator $w(h, B) = \frac{(\epsilon(h)B)^2}{8} (x_1^2 + x_2^2) - \frac{ \epsilon(h)B}{2} hL_3 ,$ where the operator $hL_3$ is the third component of the usual angular momentum operator and is the quantization of $\ell_3$. The unbounded Zeeman perturbation is controlled using localization properties of both the hydrogen atom coherent states $\Psi_{\alpha,N}$, and their derivatives $L_3(h)\Psi_{\alpha,N}$, in the large quantum number regime $N\rightarrow\infty$.