# Direct link between boson-peak modes and dielectric $\alpha$-relaxation in glasses

## TL;DR

This paper develops a microscopic theoretical framework linking boson-peak vibrational modes to dielectric alpha-relaxation in glasses, successfully matching experimental data and explaining key relaxation features.

## Contribution

It introduces a new approach connecting boson-peak modes with dielectric relaxation, improving agreement with experiments and explaining relaxation asymmetry and stretched-exponential behavior.

## Key findings

- Good agreement with experimental dielectric response of glycerol
- Supports presence of soft modes at zero eigenfrequency
- Explains alpha-peak asymmetry and stretched-exponential relaxation

## Abstract

We compute the dielectric response of glasses starting from a microscopic system-bath Hamiltonian of the Zwanzig-Caldeira-Leggett type and using an ansatz from kinetic theory for the memory function in the resulting Generalized Langevin Equation. The resulting framework requires the knowledge of the vibrational density of states (DOS) as input, that we take from numerical evaluation of a marginally-stable harmonic disordered lattice, featuring a strong boson peak (excess of soft modes over Debye $\sim\omega_{p}^{2}$ law). The dielectric function calculated based on this ansatz is compared with experimental data for the paradigmatic case of glycerol at $T\lesssim T_{g}$. Good agreement is found for both the reactive (real part) of the response and for the $\alpha$-relaxation peak in the imaginary part, with a significant improvement over earlier theoretical approaches, especially in the reactive modulus. On the low-frequency side of the $\alpha$-peak, the fitting supports the presence of $\sim \omega_{p}^{4}$ modes at vanishing eigenfrequency as recently shown in [Phys. Rev. Lett. 117, 035501 (2016)]. $\alpha$-wing asymmetry and stretched-exponential behaviour are recovered by our framework, which shows that these features are, to a large extent, caused by the soft boson-peak modes in the DOS.