Ideal strength of two-dimensional stanene may reach or exceed Griffith strength estimate

TL;DR

This study uses first-principles calculations to show that stanene, a 2D material, can potentially reach or surpass the theoretical maximum strength limit known as Griffith strength, indicating exceptional mechanical properties.

Contribution

The paper demonstrates through density functional theory that stanene's ideal strength may exceed the Griffith limit, a novel insight into 2D material strength bounds.

Findings

Stanene's strength can reach ~E/7.4 under tension.

Stanene can approach or exceed Griffith strength limit.

No phonon instability or failure observed at high strength.

Abstract

The ideal strength is the maximum stress a material can withstand, and it is an important intrinsic property for structural applications. Griffith strength limit ~E/9 is the best known upper bound of this property for a material loaded in tension. Here we report that stanene, a recently fabricated two-dimensional material, could approach and possibly exceed this limit from a theoretical perspective. Utilizing first-principles density functional theory, we investigated the nonlinear elastic behavior of stanene and found that its strength could reach ~E/7.4 under uniaxial tension in both armchair and zigzag directions without incurring phonon instability or mechanical failure. The unique mechanical properties of stanene are further appreciated by comparisons with two other Group-IV 2D materials, graphene and silicene.