Nickel Hexacyanoferrate Electrodes for Continuous Cation Intercalation Desalination of Brackish Water

TL;DR

This paper demonstrates a novel capacitive deionization device using nickel hexacyanoferrate electrodes that enables continuous, selective brackish water desalination through cation intercalation, with promising results for ion separation efficiency.

Contribution

The study introduces a new intercalation electrode-based desalination device with continuous operation and ion selectivity, advancing capacitive deionization technology.

Findings

Successful continuous desalination with NiHCF electrodes.

Threefold selectivity enhancement for K+ over Na+.

Analysis of energy consumption and salt removal rates.

Abstract

Using porous electrodes containing nickel hexacyanoferrate (NiHCF) nanoparticles, we construct and test a device for capacitive deionization in a two flow-channel device where the intercalation electrodes are in direct contact with an anion-exchange membrane. Upon negatively charging NiHCF, cations intercalate into it and the water in its vicinity is desalinated; at the same time water in the opposing electrode becomes more saline upon positively charging the NiHCF in that electrode. In a cyclic process of charge and discharge, fresh water is continuously produced, alternating between the two channels in sync with the direction of applied current. We present proof-of-principle experiments of this technology for single salt solutions, where we analyze various levels of current and cycle durations. We analyze salt removal rate and energy consumption. In desalination experiments with salt mixtures we find a threefold enhancement for K$^+$ over Na$^+$-adsorption, which shows the potential of NiHCF intercalation electrodes for selective ion separation from mixed ionic solutions.