Rotational and translational diffusion of anisotropic gold nanoparticles in liquid crystals controlled by varying surface anchoring

TL;DR

This study investigates how anisotropic gold nanoparticles diffuse in nematic liquid crystals, revealing shape, surface, and alignment-dependent anisotropic diffusion, with controllable diffusivity via surface functionalization and photoisomerization.

Contribution

It provides new insights into the anisotropic diffusion behavior of anisotropic nanoparticles in liquid crystals and demonstrates in situ control of their diffusivity through surface chemistry.

Findings

Diffusion is strongly anisotropic and depends on nanoparticle shape and surface functionalization.

Aligned nanoparticles diffuse faster along the director, while perpendicular orientations diffuse faster in the perpendicular direction.

Surface functionalization with photosensitive groups enables control of diffusivity via light-induced isomerization.

Abstract

We study translational and rotational diffusion of anisotropic gold nanoparticles (NPs) dispersed in the bulk of a nematic liquid crystal fluid host. Experimental data reveal strong anisotropy of translational diffusion with respect to the uniform far-field director, which is dependent on shape and surface functionalization of colloids as well as on their ground-state alignment. For example, elongated NPs aligned parallel to the far-field director translationally diffuse more rapidly along the director whereas diffusion of NPs oriented normal to the director is faster in the direction perpendicular to it while they are also undergoing elasticity-constrained rotational diffusion. To understand physical origins of these rich diffusion properties of anisotropic nanocolloids in uniaxially anisotropic nematic fluid media, we compare them to diffusion of prolate and oblate ellipsoidal particles in isotropic fluids as well as to diffusion of shape-isotropic particles in nematic fluids. We also show that surface functionalization of NPs with photosensitive azobenzene groups allows for in situ control of their diffusivity through trans-cis isomerization that changes surface anchoring.