Anomalous Hardening in Magnesium Driven by a Size-Dependent Transition in Deformation Modes

TL;DR

This study investigates how crystal size influences deformation modes in magnesium, revealing a size-dependent transition from twinning to dislocation plasticity, which impacts its mechanical properties and potential applications.

Contribution

It provides a comprehensive experimental and modeling analysis of size effects on deformation modes in twin-oriented Mg crystals, highlighting a transition point around 18 μm.

Findings

Smaller than 18 μm, Mg exhibits size-strengthening behavior.

Larger than 18 μm, twin-twin interactions cause anomalous strain hardening.

Molecular dynamics shows a transition from twinning to dislocation-mediated plasticity at nanoscale sizes.

Abstract

Magnesium (Mg) and its alloys hold great potential as an energy-saving structural material for automative, aerospace applications. However, the use of Mg alloys has been limited due to poor ductility and formability. Poor mechanical properties of Mg alloys origin from the insufficient number of slip systems, and deformation twinning plays an important role to accommodate plastic deformation. Here, we report a comprehensive experimental and modeling study to understand crystal size effect on the transformation in deformation modes in twin oriented Mg single crystals. The experiments reveal two regimes of size effects: (1) single twin propagation, where a typical "smaller the stronger" behavior was dominant in pillars {\le} 18 {\mu}m in diameter, and (2) twin-twin interaction, which results in anomalous strain hardening in pillars > 18 {\mu}m. Molecular dynamics simulations further indicate a transition from twinning to dislocation mediated plasticity for crystal sizes below a few hundred nanometers. Our results provide new understanding of the fundamental deformation modes of twin oriented Mg from nano-scale to bulk, and insights to design Mg alloys with superior mechanical properties through dimensional refinement. This subsequently can materialize into more utilization of Mg alloys as a structural material in technologically relevant applications.