Exceptional magneto-electric coupling and spontaneous electric polarization in anti-ferromagnet Co4Nb2O9

TL;DR

This study demonstrates that polycrystalline Co4Nb2O9 exhibits strong magneto-electric coupling and spontaneous electric polarization below its Neel temperature, confirming its multiferroic nature with potential for multifunctional applications.

Contribution

The paper provides comprehensive structural and physical characterizations of Co4Nb2O9, establishing it as a genuine multiferroic material with notable magneto-electric effects and spontaneous polarization.

Findings

Co4Nb2O9 becomes antiferromagnetic at ~28 K.

Strong magneto-electric coupling observed below TN.

Spontaneous electric polarization confirmed in AFM state.

Abstract

Synthesis and extensive structural, pyroelectric, magnetic, dielectric and magneto-electric characterizations are reported for polycrystalline Co4Nb2O9 towards unraveling the multiferroic state especially in reference to the magnetic spin flop transition. Magnetic measurements confirm the Co4Nb2O9 becomes antiferromagnetic (AFM) at around 28 K but no clear evidence for spin-flop effect was found. Associated with the magnetic phase transition, a sharp peak in pyroelectric current indicates the appearance of the strong magneto-electric coupling below Neel temperature (TN) with a large coupling constant upto 17.8 uC/m^2T. Using temperature oscillation technique, we establish Co4Nb2O9 to be a genuine multiferroic with spontaneous electric polarization in the anti-ferromagnetic state.