Cavity Born-Oppenheimer Approximation for Correlated Electron-Nuclear-Photon Systems

TL;DR

This paper details the cavity Born-Oppenheimer approximation for correlated electron-nuclear-photon systems, demonstrating its effectiveness in describing eigenstates and dynamics in strongly coupled light-matter systems, with implications for ab-initio modeling.

Contribution

It introduces and demonstrates the cavity Born-Oppenheimer approximation for correlated light-matter systems, enabling accurate eigenstate and dynamic descriptions.

Findings

Ground-state potential energy surfaces can develop double-well structures.

Photon modes can be dressed, altering harmonic potentials.

Population transfer between potential energy surfaces explains dynamics.

Abstract

In this work, we illustrate the recently introduced concept of the cavity Born-Oppenheimer approximation for correlated electron-nuclear-photon problems in detail. We demonstrate how an expansion in terms of conditional electronic and photon-nuclear wave functions accurately describes eigenstates of strongly correlated light-matter systems. For a GaAs quantum ring model in resonance with a photon mode we highlight how the ground-state electronic potential-energy surface changes the usual harmonic potential of the free photon mode to a dressed mode with a double-well structure. This change is accompanied by a splitting of the electronic ground-state density. For a model where the photon mode is in resonance with a vibrational transition, we observe in the excited-state electronic potential-energy surface a splitting from a single minimum to a double minimum. Furthermore, for a time-dependent setup, we show how the dynamics in correlated light-matter systems can be understood in terms of population transfer between potential energy surfaces. This work at the interface of quantum chemistry and quantum optics paves the way for the full ab-initio description of matter-photon systems.