Microstructural and transport properties of superconducting FeTe0.65Se0.35 crystals

TL;DR

This study investigates how microstructural inhomogeneities and chemical disorder in FeTe0.65Se0.35 crystals affect their superconducting transport properties, revealing that nanoscale phase separation and inhomogeneity can enhance superconductivity.

Contribution

It provides new insights into the impact of microstructural inhomogeneities and nanoscale phase separation on the superconducting properties of FeTe0.65Se0.35 crystals.

Findings

Chemical disorder influences superconducting properties.

Inhomogeneities and nanoscale phase separation can enhance superconductivity.

Weak superconducting links cause local property variations.

Abstract

The issue concerning the nature and the role of microstructural inhomogeneities in iron chalcogenide superconducting crystals of FeTe0.65Se0.35 and their correlation with transport properties of this system was addressed. Presented data demonstrate that chemical disorder originating from the kinetics of the crystal growth process significantly influences the superconducting properties of an Fe-Te-Se system. Transport measurements of the transition temperature and critical current density performed for microscopic bridges allow us to deduce the local properties of a superconductor with microstructural inhomogeneities, and significant differences were noted. The variances observed in the local properties were explained as a consequence of weak superconducting links existing in the studied crystals. The results confirm that inhomogeneous spatial distribution of ions and small hexagonal symmetry nanoscale regions with nanoscale phase separation also seem to enhance the superconductivity in this system with respect to the values of the critical current density. Magnetic measurements confirm the conclusions drawn from the transport measurements.